What absorbs at 1992 cm⁻¹ in an FTIR spectrum?
A band near 1992 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 8 cited sources
Quick answer
A band near 1992 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
可能的官能团归属
| 官能团 | 支持性事实 | 引用来源 | 最高置信度 |
|---|---|---|---|
| Aromatic ring | 3 | 3 | 1.0 |
| Amide | 3 | 2 | 1.0 |
| N h | 2 | 2 | 1.0 |
| Methoxy (OCH3) | 2 | 2 | 1.0 |
| Methacrylate | 2 | 2 | 1.0 |
| C-O single bond | 2 | 2 | 1.0 |
| Acetate | 2 | 2 | 1.0 |
| Secondary amine | 1 | 1 | 1.0 |
| Protein | 1 | 1 | 1.0 |
| Alkene (C=C) | 1 | 1 | 1.0 |
| Alkyl C-H | 1 | 1 | 1.0 |
排名反映了累积的文献证据,而非单一的权威规则。请始终对照您的样品背景进行确认。
Possible materials
| 材料 | 支持峰 | Overlapping groups | 引用来源 |
|---|---|---|---|
| gelatin | 1992, 1652, 3300 | Amide, N h | 2 |
| silver nanoparticles | 1992, 1636, 1631 | Amide, N h, Methoxy (OCH3) | 2 |
| Polyethylene | 1992, 1737, 1720 | Methoxy (OCH3), Aromatic ring | 1 |
| Pt | 1992, 1042, 1230 | Methoxy (OCH3) | 1 |
Materials are shown only when the same literature pool supports this band and at least one additional characteristic peak.
Spectrum logic
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 1992 cm⁻¹ is usually not enough for material identification by itself.
Real-world usage
This type of query is common in polymer identification, unknown plastic screening, QC troubleshooting, recycled-material verification, and literature-backed peak assignment review.
Common mistakes
- Treating one isolated band as proof of a material without checking at least one or two supporting peaks.
- Ignoring overlap: multiple functional groups can contribute near the same wavenumber.
- Skipping validation when additives, blends, oxidation, or contamination may distort the spectrum.
Verification advice
When ambiguity remains, validate the hypothesis with DSC, GC-MS, or TGA, especially for blends, degraded samples, and filled polymers.
这些分配背后的文献
-
Alkyl C-H 置信度 1.0
“Indian J Exp Biol C-H droxy group,H-bonded OH stretch, methylene stretch in James AA (1992) Mosquito molecular genetics: the hands that feed bite 257:37-38 back.”
Marimuthu 等 - 2013 - Eco-friendly microbial route to synthesize cobalt DOI: 10.1007/s00436-013-3601-2 -
置信度 1.0
“The Amide II band is due to combination of a C-N N 325 stretch and N-H deformation in the gelatin structure (Bandekar, 1992).”
Rheological, micro-structural and sensorial properties of camel milk yogurt as influenced by gelatin DOI: 10.1016/j.lwt.2018.09.008 -
Acetate 置信度 1.0
“The peaks at 1757 and 1200 are attributed to the 22,p.97,J.O'M.Bockris,B.E.Conway,B.E.White,Editors,PlenumPress,New mode25 carbonyl stretching and C-O-C stretching modes of ~1992!.”
Sanicharane 等 - 2002 - In situ 50 degrees C FTIR spectroscopy of Pt and P DOI: 10.1149/1.1464883 -
Alkene (C=C) 置信度 1.0
“thiocyanate, or isothiocyanate (-NCS) (monosubstituted) GSE-AgNPs 1634 Medium Alkenyl C=C stretch Olefinic alkene 1992/1966 Weak Aromatic combination bands Aromatic ring Transition metal carbonyls, The GC/MS analysis of GSE showed the prese”
The Antimicrobial Activities of Silver Nanoparticles from Aqueous Extract of Grape Seeds against Pathogenic Bacteria and Fungi DOI: 10.3390/molecules26196081 -
Amide 置信度 1.0
“Saudi Pharm J 25:861-867 Bandekar J (1992) Amide modes and protein conformation.”
Theranostic RGD@Fe3O4-Au/Gd NPs for the targeted radiotherapy and MR imaging of breast cancer DOI: 10.1186/s12645-023-00214-6 -
Aromatic ring 置信度 1.0
“The bands at 1421 and cm-1 1418 in PP and PS were assigned to the C-H deformation in methoxyl and aromatic skeletal vibrations in lignin (Faix 1992;”
Elmas 和 Yilgor - 2020 - Chemical and Thermal Characterizations of Pinus sy DOI: 10.1515/hf- -
Acetate 置信度 1.0
“C-O C¼O and as the stretching gives a signal less intense than the stretching, this Carlsson,1992;”
One year monitoring by FTIR of γ-irradiated multilayer film PE/EVOH/PE DOI: 10.1016/j.radphyschem.2016.03.010 -
Amide 置信度 1.0
“The C-N stretching vibrations coupled with N-H inplane bending vibrations, weak contributions from C-C bond stretching vibrations and C=O in-plane bending give rise to Amide III absorption (Bandekar 1992).”
Irfanita 等 - 2022 - Attenuated Total Reflectance-Fourier Transform Inf DOI: 10.21315/tlsr2022.33.2.7
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