What absorbs at 1353 cm⁻¹ in an FTIR spectrum?
A band near 1353 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 6 cited sources
Quick answer
A band near 1353 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
가능한 작용기 할당
| 작용기 | 지원 사실 | 인용 출처 | 최고 신뢰도 |
|---|---|---|---|
| Amide | 2 | 2 | 1.0 |
| Alkyl C-H | 1 | 1 | 1.0 |
| Ring structure | 1 | 1 | 1.0 |
| Methoxy (OCH3) | 1 | 1 | 1.0 |
| Methacrylate | 1 | 1 | 1.0 |
| C-O single bond | 1 | 1 | 1.0 |
| Acetate | 1 | 1 | 1.0 |
| Secondary amine | 1 | 1 | 1.0 |
| C n single bond | 1 | 1 | 1.0 |
| Carboxyl (COOH) | 1 | 0 | 1.0 |
순위는 단일 권위 규칙이 아닌 축적된 문헌 증거를 반영합니다. 항상 샘플 상황에 대해 확인하세요.
Possible materials
Materials are shown only when the same literature pool supports this band and at least one additional characteristic peak.
Spectrum logic
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 1353 cm⁻¹ is usually not enough for material identification by itself.
Real-world usage
This type of query is common in polymer identification, unknown plastic screening, QC troubleshooting, recycled-material verification, and literature-backed peak assignment review.
Common mistakes
- Treating one isolated band as proof of a material without checking at least one or two supporting peaks.
- Ignoring overlap: multiple functional groups can contribute near the same wavenumber.
- Skipping validation when additives, blends, oxidation, or contamination may distort the spectrum.
Verification advice
When ambiguity remains, validate the hypothesis with DSC, GC-MS, or TGA, especially for blends, degraded samples, and filled polymers.
이 할당의 배경이 되는 문헌
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Amide 신뢰도 1.0
“cm-1 cm-1 cm-1 cm-1 to 720 (a) and from 1850 to 1300 (b) ranging from 1850 070007-4 In PEI-F-ICJ spectrum, the intensity of bands relative to asymmetric stretching vibration of carbonyl imide (1722 cm-1) cm-1) and C-N stretching vibration (”
Sonego 等 - 2016 - Chemical Changes in Polyetherimide (PEI) Joined by DOI: 10.1063/1.4965539 -
Acetate 신뢰도 1.0
“The band at 1353 cm-1 can be attributed to C-O-H bending cm-1 cm-1 OH deformation in the band at 1474 [44,45].”
Pore Blocking by Phenolates as Deactivation Path during the Cracking of 4-Propylphenol over ZSM-5 DOI: 10.3390/catal11060721 -
Alkyl C-H 신뢰도 1.0
“cm-1, C-H new bands at 1353 and 848 corresponding to the Consequently, the resulting hydrogel would assume a cm-1, Cbending vibration, and at 1252 corresponding to the ∼71 composition containing wt % lignin.”
Teng 等 - 2017 - Preparation and Properties of Hydrogels Based on P DOI: 10.1021/acsomega.6b00296 -
Amide 신뢰도 1.0
“The band at cm-1 corresponds to the amide groups of proteins which could be released by aromatic carbon 1638.38 compounds and carbon double bonds as well as alkene groups (-C-H stretch) [50], while these at 1399.65, 1384.55 cm-1 1081.96cm-1”
Wypij 等 - 2022 - Novel Antibacterial, Cytotoxic and Catalytic Activ DOI: 10.4014/jmb.2205.05006 -
신뢰도 0.9
“Explicit assignment: disorder (D-band).”
Optimization and Characterization of Mesoporous Sulfonated Carbon Catalyst and Its Application in Modeling and Optimization of Acetin Production DOI: 10.3390/molecules25225221 -
신뢰도 0.9
“Explicitly assigned as D band.”
Extracellular electron uptake from carbon-based π electron surface-donors: oxidation of graphite sheets by Sulfobacillus thermosulfidooxidans probed by Raman and FTIR spectroscopies DOI: 10.1039/c9ra03628h
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