What absorbs at 1278 cm⁻¹ in an FTIR spectrum?
A band near 1278 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 8 cited sources
Ātra atbilde
A band near 1278 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
Iespējamie funkcionālo grupu piešķīrumi
| Funkcionālā grupa | Atbalstošie fakti | Citētie avoti | Augstākā pārliecība |
|---|---|---|---|
| Methoxy (OCH3) | 8 | 7 | 1,0 |
| Methacrylate | 8 | 7 | 1,0 |
| C-O single bond | 8 | 7 | 1,0 |
| Acetate | 8 | 7 | 1,0 |
| Alkyl C-H | 3 | 3 | 1,0 |
| Hydroxyl (O-H) | 2 | 2 | 1,0 |
| Protein | 1 | 1 | 1,0 |
| Carbonyl (C=O) | 1 | 1 | 0,9 |
Rangs atspoguļo uzkrātos literatūras pierādījumus, nevis vienu autoritatīvu noteikumu. Vienmēr apstipriniet atbilstoši parauga kontekstam.
Iespējamie materiāli
| Materiāls | Atbalstošie pīķi | Pārklājošās grupas | Citētie avoti |
|---|---|---|---|
| PEG | 1278, 1650, 1342 | Methacrylate, Acetate, C-O single bond | 1 |
| Fe3O4 | 1278, 2358, 1673 | Methacrylate, Acetate | 1 |
| polymers | 1278, 1726, 1743 | Methacrylate, Acetate, C-O single bond | 1 |
| collagen | 1278, 1408, 1660 | Methacrylate, Acetate, Methoxy (OCH3) | 1 |
Materiāli tiek parādīti tikai tad, ja šo joslu un vismaz vienu papildu raksturīgo pīķi atbalsta tā pati literatūras kopa.
Spektra loģika
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 1278 cm⁻¹ is usually not enough for material identification by itself.
Reālās pasaules izmantošana
Šāda veida vaicājums ir izplatīts polimēru identificēšanā, nezināmas plastmasas skrīningā, kvalitātes kontroles problēmu risināšanā, pārstrādāto materiālu pārbaudē un ar literatūru pamatotā pīķu piešķīruma pārskatā.
Biežākās kļūdas
- Vienas izolētas joslas uzskatīšana par materiāla pierādījumu, nepārbaudot vismaz vienu vai divus atbalsta pīķus.
- Ignorējot pārklāšanos: vairākas funkcionālās grupas var dot ieguldījumu tuvu tam pašam viļņa skaitlim.
- Izlaist validāciju, ja piedevas, maisījumi, oksidācija vai piesārņojums var izkropļot spektru.
Verifikācijas padoms
Ja joprojām pastāv neskaidrība, apstipriniet hipotēzi ar DSC, GC-MS vai TGA, īpaši maisījumiem, noārdītiem paraugiem un pildītiem polimēriem.
Literatūra aiz šiem piešķīrumiem
-
Hydroxyl (O-H) pārliecība 1,0
“The O-H and C-O-C cm-1, stretching vibrations produce peaks at 1278 and 1095 respectively [44].”
Formulation and Characterization of Fe3O4@PEG Nanoparticles Loaded Sorafenib; Molecular Studies and Evaluation of Cytotoxicity in Liver Cancer Cell Lines DOI: 10.3390/polym15040971 -
Alkyl C-H pārliecība 1,0
“The main characteristic bands at 1278 cm-1 correspond to the -CH group”
Influence of Electrospinning Parameters on Fiber Diameter and Mechanical Properties of Poly(3-Hydroxybutyrate) (PHB) and Polyanilines (PANI) Blends DOI: 10.3390/polym8030097 -
Acetate pārliecība 1,0
“618 cm-1 cm-1 vibrations), 1509 (C=O and C=C vibrations), 1428 (olefinic C-H bending vibrations), cm-1 cm-1 1278 (aromatic C-O stretching vibrations), 1024 (C-O-C stretching vibrations) [13].”
Ahmed 等 - 2021 - STRUCTURAL AND OPTICAL CHARACTERISTICS OF POLY(VIN DOI: 10.4314/bcse.v35i3.12 -
Hydroxyl (O-H) pārliecība 1,0
“In addition, two other cm-1 the nanoparticles in the formulation can be utilized for characteristic bands are observed at 1278 and 1058 O-H C-O-H target the cancer cells by the application of external magwhich belongs to the and stretching”
Ebadi 等 - 2019 - Synthesis and properties of magnetic nanotheranost DOI: 10.2147/IJN.S214923 -
Alkyl C-H pārliecība 1,0
“Biomolecules 2021, 11, x FOR PEER REVIEW 4 of 20 the peaks at 1343 cm-1 and 1278 cm-1 to rocking vibration modes of CH2 [48], while the is indicative of the OH deformation asymmetric ring mode vibration peak at 1209 cm-1 Biomolecules2021,11”
Stabilization of Dry Sucrose Glasses by Four LEA_4 Proteins from Arabidopsis thaliana DOI: 10.3390/biom11050615 -
Protein pārliecība 1,0
“The centroid spectrum corresponding to fibrosis tissue was characterized by absorbance peaks related to vibrational modes of collagen as evidenced by the peaks at 1174 cm-1 (C-O stretching) [34], 1202 cm-1, 1230 cm-1, 1278 cm-1, 1304 cm-1 (”
Moreau 等 - 2020 - Analysis of Hepatic Fibrosis Characteristics in Ci DOI: 10.3390/molecules25184092 -
Acetate pārliecība 1,0
“The CH asymmetric and symmetric deformation was observed at 1452 and 3 cm-1 cm-1, cm-1, 1379 respectively, whilst C-O-C stretching was observed at 1278 1224”
Development of an Electrospun Patch Platform Technology for the Delivery of Carvedilol in the Oral Mucosa DOI: 10.3390/nano12030438 -
Acetate pārliecība 1,0
“The most pronounced chemical groups of PHB correspond to the peaks at 1721 cm-1 (C=O group), 1052 cm-1 (C-O-C group), 1278 cm-1 (CH group), and 3000-2700 cm-1 (-C-H”
Development of Nonwoven Fibrous Materials Based on Poly-3-Hydroxybutyrate with a High Content of -Tricalcium Phosphate DOI: 10.3390/polym15153167
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