What absorbs at 1204 cm⁻¹ in an FTIR spectrum?
A band near 1204 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 8 cited sources
빠른 답변
A band near 1204 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
가능한 작용기 할당
| 작용기 | 지원 사실 | 인용 출처 | 최고 신뢰도 |
|---|---|---|---|
| C-O single bond | 8 | 7 | 1.0 |
| Methoxy (OCH3) | 6 | 5 | 1.0 |
| Methacrylate | 6 | 5 | 1.0 |
| Acetate | 6 | 5 | 1.0 |
| Alkyl C-H | 4 | 4 | 1.0 |
| Amide | 3 | 3 | 1.0 |
| Protein | 3 | 2 | 1.0 |
| Hydroxyl (O-H) | 2 | 2 | 1.0 |
| Fluorine (C-F) | 2 | 2 | 1.0 |
| S eq o | 1 | 1 | 1.0 |
| Aromatic ring | 1 | 1 | 1.0 |
| Hydrogen bond | 1 | 1 | 1.0 |
| Water (H2O) | 1 | 1 | 1.0 |
순위는 단일 권위 규칙이 아닌 축적된 문헌 증거를 반영합니다. 항상 샘플 상황에 대해 확인하세요.
스펙트럼 로직
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 1204 cm⁻¹ is usually not enough for material identification by itself.
실제 사용
이러한 유형의 질의는 고분자 식별, 미지 플라스틱 스크리닝, QC 문제 해결, 재활용 재료 검증 및 문헌 기반 피크 할당 검토에서 일반적입니다.
일반적인 실수
- 하나의 고립된 밴드를 재료의 증거로 취급하고 최소 하나 또는 두 개의 지원 피크를 확인하지 않는 것.
- 겹침 무시: 여러 작용기가 동일한 파수 근처에서 기여할 수 있습니다.
- 첨가제, 혼합물, 산화 또는 오염이 스펙트럼을 왜곡할 수 있는 경우 검증을 건너뜁니다.
검증 조언
모호성이 남아 있는 경우, 특히 혼합물, 분해된 시료 및 충전 폴리머의 경우 DSC, GC-MS 또는 TGA로 가설을 검증하십시오.
이 할당의 배경이 되는 문헌
-
Acetate 신뢰도 1.0
“C-O stretching vibration C-F 1204, 1148 1203, 1149 C-F stretching PFOA-modified”
Ganie 等 - 2020 - Synthesis and Characterization of a New Surface-Mo DOI: 10.1155/2020/8814260 -
C-O single bond 신뢰도 1.0
“The peaks at 1204 and 1036 Figure 3) was considered to arise from many 0% RH belonged to C-OH in plane bending types of adsorbed water.”
Characterizing molecular structure of water adsorbed by cellulose nanofiber film using in situ micro-ftir spectroscopy DOI: 10.1080/02773813.2017.1306078 -
Alkyl C-H 신뢰도 1.0
“O iment showed that during this degradation step, the bromine A articles groups of the polymer end functionalities are eliminated, and cm-1 the peaks at 1204 and 1164 correspond to the CH wagare governed ging vibrations of CH 3Br.”
Aliyev 等 - 2020 - SI-ATRP Polymer-Functionalized Graphene Oxide for DOI: 10.1002/admi.202000443. -
Amide 신뢰도 1.0
“Its presence interferes with the detection of the Amide III series of bands (1337, 1284, 1240 cm-1) and 1204 cm-1) but these would not be prominent in the perpendicular orientation.”
Orientation Matters: Polarization Dependent IR Spectroscopy of Collagen from Intact Tendon Down to the Single Fibril Level DOI: 10.3390/molecules25184295 -
신뢰도 1.0
“Mcintosh et al.[7] had shown that the absorbance bands assigned to collagen (1035, 1080, 1204, cm-1) 1240, 1280, and 1330 were only observed in the dermis.”
Hammody 等 - 2005 - Characterization of malignant melanoma using vibra DOI: 10.1100/tsw.2005.1 -
Hydrogen bond 신뢰도 1.0
“electronic ground state were largely identical and gave limited Immediately after photoexcitation (Figure 2b, black line), information on the prevailing hydrogen bond patterns in these strong peaks appeared at 1204, 1258, 1284, 1349, 1386,”
Spectroscopic and Computational Observation of Glutamine Tautomerization in the Blue Light Sensing Using Flavin Domain Photoreaction DOI: 10.1021/jacs.2c10621 -
Hydroxyl (O-H) 신뢰도 1.0
“The C-O stretching and C-C stretching was detected at 1440 [27], cm-1 cm-1 C-N stretching at 1340 [21] and C-O stretching or O-H bending at 1204 [27].”
Discrimination of Syzygium samarangense cv. ‘Giant Green’ Leaves at Different Maturity Stages by FTIR and GCMS Fingerprinting DOI: 10.3390/horticulturae9050609 -
C-O single bond 신뢰도 1.0
“The very cm-1 wavenumbers correspond to C-F stretching vibrations of the PTFE strong absorption bands near 1144 and 1204 cm-1 are assigned to the symmetric vibrations of two ether backbone in Nafion.”
Irmawati 等 - 2016 - Polarization Losses Under Dynamic Load Cycle Using DOI: 10.1063/1.4941635
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