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The FTIR evidence does not support a firm identification as Morpholine-4-carbonitrile. The spectrum is better described more broadly as an oxygen-containing aliphatic organic material, likely also containing nitrogen by library trend, with strong C-O-type absorptions and a prominent carbonyl-like band near 1721 cm-1. This makes a narrow heterocyclic nitrile assignment unsafe on the present evidence
Recommended next steps: Re-examine the full spectrum specifically for any band in the 2200-2260 cm-1 region to test whether a nitrile group is actually present. Inspect the 1700-1750 cm-1 band shape and intensity in the raw spectrum to determine whether the 1721 cm-1 feature is a true ester-like carbonyl or could arise from overlap or background effects. Compare the sample against reference spectra for oxygenated aliphatic materials such as simple esters, alkoxy-containing carbonyl compounds, and morpholine derivatives before accepting any nitrogen-heterocycle assignment. If available, confirm composition with a complementary method such as GC-MS or LC-MS for molecular identity, or elemental analysis to check whether nitrogen is present at all.
| Rank | Match % | Compound | SMILES | Spectrum No. | Action |
|---|---|---|---|---|---|
| Loading library candidates... | |||||
| # | Wavenumber (cm⁻¹) | Absorbance | Assignment | Citation | Assignment status | |
|---|---|---|---|---|---|---|
| 1 | · | 869 | 1.00 | - | - | - |
| 2 | · | 1409 | 0.84 | - | - | - |
| 3 | · | 1721 | 0.41 | - | - | - |
| 4 | · | 1255 | 0.37 | - | - | - |
| 5 | · | 1262 | 0.37 | - | - | - |
| 6 | · | 1117 | 0.37 | - | - | - |
| 7 | · | 954 | 0.33 | - | - | - |
| 8 | · | 738 | 0.28 | - | - | - |
| 9 | · | 703 | 0.26 | - | - | - |
| 10 | · | 1068 | 0.25 | - | - | - |
| 11 | · | 2928 | 0.21 | - | - | - |
| 12 | · | 2961 | 0.20 | - | - | - |
| 13 | · | 2859 | 0.13 | - | - | - |
| 14 | · | 1033 | 0.11 | - | - | - |
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