What absorbs at 944 cm⁻¹ in an FTIR spectrum?
A band near 944 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 7 cited sources
Hiter odgovor
A band near 944 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
Možne dodelitve funkcionalnih skupin
| Funkcionalna skupina | Podporna dejstva | Citirani viri | Najvišje zaupanje |
|---|---|---|---|
| Alkyl C-H | 4 | 3 | 1,0 |
| Methoxy (OCH3) | 4 | 3 | 1,0 |
| Methacrylate | 4 | 3 | 1,0 |
| Acetate | 4 | 3 | 1,0 |
| C-O single bond | 3 | 3 | 1,0 |
| Ring structure | 2 | 1 | 1,0 |
| Hydroxyl (O-H) | 2 | 1 | 1,0 |
| Chlorine | 1 | 1 | 1,0 |
| Siloxane (Si-O-Si) | 1 | 1 | 1,0 |
| Silicon-oxygen (Si-O) | 1 | 1 | 1,0 |
| Carbohydrate | 1 | 1 | 1,0 |
| Carboxyl (COOH) | 1 | 0 | 1,0 |
| Methyl | 1 | 0 | 1,0 |
Razvrstitev odraža zbrane literaturne dokaze, ne enega avtoritativnega pravila. Vedno preverite glede na kontekst vašega vzorca.
Možni materiali
| Material | Podporni vrhovi | Prekrivajoče se skupine | Citirani viri |
|---|---|---|---|
| chitosan | 944, 1650, 1655 | Alkyl C-H, Acetate, Methacrylate | 1 |
Materiali so prikazani le, ko ista literaturna podlaga podpira ta pas in vsaj en dodatni karakteristični vrh.
Logika spektra
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 944 cm⁻¹ is usually not enough for material identification by itself.
Uporaba v resničnem svetu
Ta vrsta poizvedbe je pogosta pri identifikaciji polimerov, pregledovanju neznanih plastičnih mas, odpravljanju težav pri QC, preverjanju recikliranih materialov in literaturno podprtem pregledu dodelitev vrhov.
Pogoste napake
- Obravnavanje enega izoliranega pasu kot dokaza o materialu brez preverjanja vsaj enega ali dveh podpornih vrhov.
- Ignoriranje prekrivanja: več funkcionalnih skupin lahko prispeva blizu istega valovnega števila.
- Izpuščanje validacije, ko lahko dodatki, mešanice, oksidacija ali kontaminacija popačijo spekter.
Nasvet za preverjanje
Ko ostaja dvoumnost, potrdite hipotezo z DSC, GC-MS ali TGA, zlasti za mešanice, degradirane vzorce in polnjene polimere.
Literatura za temi dodelitvami
-
Acetate zaupanje 1,0
“The cm-1 peak at 944 observed in the as-burnt BCZT powder with pH 5 was related to C-O-H bending vibration which was in agreement with previous work [13].”
Influence of pH values on the surface and properties of BCZT nanopowders synthesized via sol-gel auto-combustion method DOI: 10.1016/j.surfcoat.2016.03.091 -
zaupanje 1,0
“These peaks 943.88 and 968.32 eV correspond to Cu(II) species at the Cu 2O surface [52].”
Synthesis of CaCO3/Cu2O/GO Nanocomposite Catalysts for Hydrogen Production from NaBH4 Methanolysis DOI: 10.3390/catal13061010 -
Carbohydrate zaupanje 1,0
“Finally, absorptions at 944 and 841 were assigned to the pyranose ring.”
Gabriela Chuc-Gamboa 等 - 2021 - Antibacterial Behavior of Chitosan-Sodium Hyaluron DOI: 10.3390/app1103 -
zaupanje 1,0
“silanol Si-O stretch 944 Si-O-Si symmetric stretch 802 C-H3Asymmetric stretch 2954, 2955, 2961 C-H3Symmetric stretch”
<32352D382D3032283433322D3433372920C1A4BCF6B1A420C0AFBDBDB1E220C0E5BDBDBED620B9DAC1F8BCBA20B1E8C5C2C7F620C0CCC1A4C8C620B1E8BCF6B9CE2E687770> DOI: 10.6110/KJACR.2013.25.8.432 -
Acetate zaupanje 1,0
“The peaks saw at 944.5, prepared sample is calculated by using Debye-Scherrer's formula, cm(cid:3)1 C-O C-O 1105.6 and 1569.2 are assigned to aliphatic bending, C¼O film.”
Effect of Al2O3 on structural and dielectric properties of PVP-CH3COONa based solid polymer electrolyte films for energy storage devices DOI: 10.1016/j.heliyon.2019.e02727 -
Alkyl C-H zaupanje 1,0
“There are two strong absorption Figure 4c represents the IR spectrum of cationic sago starch at the optimum condition with DS bands at 944 cm-1 and 1081 cm-1 corresponded to an alkyl halide, C-Cl and C-O stretching, 1.195.”
Preparation and Optimization of Water-Soluble Cationic Sago Starch with a High Degree of Substitution Using Response Surface Methodology DOI: 10.3390/polym12112614 -
Alkyl C-H zaupanje 1,0
“cm-1-C-O and C-C stretching vibration, 1103-1020 cm-1--CH2 bending vibration, 944For the irradiated samples at 120 min, 180 min, and 240 min, two bands appear at 804 cm-1--CH bending vibration (phenyl), and 779-745 cm-1-C-O-C bending vibrac”
Optical Characterization of Ciprofloxacin Photolytic Degradation by UV-Pulsed Laser Radiation DOI: 10.3390/molecules26082324
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