What absorbs at 845 cm⁻¹ in an FTIR spectrum?
A band near 845 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 8 cited sources
Snabbt svar
A band near 845 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
Möjliga identifieringar av funktionella grupper
| Funktionell grupp | Stödjande fakta | Citerade källor | Högsta förtroende |
|---|---|---|---|
| Methoxy (OCH3) | 3 | 2 | 1,0 |
| Silicon-oxygen (Si-O) | 2 | 2 | 1,0 |
| Alkyl C-H | 2 | 2 | 1,0 |
| Silicon carbon | 2 | 2 | 1,0 |
| Metal oxygen | 2 | 2 | 1,0 |
| C c single bond | 2 | 2 | 1,0 |
| Carbohydrate | 2 | 2 | 1,0 |
| Methacrylate | 2 | 2 | 1,0 |
| Acetate | 2 | 2 | 1,0 |
| C-O single bond | 2 | 2 | 1,0 |
| Fluorine (C-F) | 1 | 1 | 1,0 |
| Silicon (Si) | 1 | 1 | 1,0 |
| Hydroxyl (O-H) | 1 | 1 | 1,0 |
| Phosphate (PO4) | 1 | 1 | 1,0 |
| Secondary amine | 1 | 1 | 1,0 |
| C n single bond | 1 | 1 | 1,0 |
| Amide | 1 | 1 | 1,0 |
| Ring structure | 1 | 1 | 1,0 |
| Aromatic ring | 1 | 1 | 1,0 |
| Sulfate (SO4) | 1 | 1 | 1,0 |
| N n bond | 1 | 1 | 1,0 |
| Oxygen heterocycle | 1 | 1 | 0,9 |
Rankingen speglar ackumulerade litteraturbevis, inte en enda auktoritativ regel. Bekräfta alltid mot din provkontext.
Möjliga material
| Material | Stödjande toppar | Överlappande grupper | Citerade källor |
|---|---|---|---|
| polypyrrole | 845, 1700, 400 | Alkyl C-H | 1 |
| PPy | 845, 1043, 910 | Alkyl C-H, Methoxy (OCH3) | 1 |
| PVA | 845, 1660, 2930 | Alkyl C-H, Methoxy (OCH3) | 1 |
Material visas endast när samma litteraturpool stöder detta band och minst en ytterligare karakteristisk topp.
Spektrumlogik
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 845 cm⁻¹ is usually not enough for material identification by itself.
Användning i verkligheten
Denna typ av fråga är vanlig inom polymeridentifiering, screening av okänd plast, felsökning av kvalitetskontroll, verifiering av återvunnet material och litteraturstödd toppidentifieringsgranskning.
Vanliga misstag
- Behandla ett isolerat band som bevis på ett material utan att kontrollera minst en eller två stödjande toppar.
- Ignorerar överlapp: flera funktionella grupper kan bidra nära samma vågtal.
- Hoppa över validering när tillsatser, blandningar, oxidation eller föroreningar kan förvränga spektrat.
Verifieringsråd
När oklarhet kvarstår, validera hypotesen med DSC, GC-MS eller TGA, särskilt för blandningar, nedbrutna prover och fyllda polymerer.
Litteratur bakom dessa identifieringar
-
Acetate förtroende 1,0
“Raw MPF spectrum shows a broad peak at cm-1 cm-1 at 845 is due to the deformation vibration of C-O-C 3395 of O-H stretching.”
Graft copolymerization of methyl methacrylate on Meizotropis Pellita fibres and their applications in oil absorbency DOI: 10.1007/s13726-020-00869-7 -
N n bond förtroende 1,0
“The bands at (n n cm-1 845 and 971 and are due to stretching vibrations of SiO and 3) and bands at 486 and N 4 1”
Driving the photoluminescent and structural properties of X2-Y2SiO5 by varying the dopant Dy3+ concentration towards cool wLED applications DOI: 10.1016/j.solidstatesciences.2017.05.008 -
Metal oxygen förtroende 1,0
“The FTIR spectrum showed the absorption band at 845 cm-1 that is due to the stretching mode of is attributed to Bi-O-Bi bond, and the strong absorption band recorded at 424 Bi-O.”
Zulkifli 等 - 2017 - Effect of Hydrothermal Reaction Time on Size of Bi DOI: 10.1063/1.5010448 -
C-O single bond förtroende 1,0
“PVAL was observed via its C-O stretching vibrations and contributed as vibrations and contributed as a shoulder of the band at 1170 cm-1 with its C-C-O cm-1 cm-1 a shoulder of the band at 1170 with its C-C-O stretching at 845 [26].”
Polypyrrole Aerogels: Efficient Adsorbents of Cr(VI) Ions from Aqueous Solutions DOI: 10.3390/gels9070582 -
Sulfate (SO4) förtroende 1,0
“Vibration bands at 830 and 845 cm-1 have previously been associated with 4-Oand 2-O-sulfate groups in agar-type polysaccharides [46].”
Exopolysaccharides Production by Cultivating a Bacterial Isolate from the Hypersaline Environment of Salar de Uyuni (Bolivia) in Pretreatment Liquids of Steam-Exploded Quinoa Stalks and Enzymatic Hydrolysates of Curupaú Sawdust DOI: 10.3390/fermentation7010033 -
Aromatic ring förtroende 1,0
“and aromatic ring vibrations at 971, 870 and 845 cm-1 (Figcm-1;”
Advantages of External Reflection and Transflection over ATR in the Rapid Material Characterization of Negatives and Films via FTIR Spectroscopy DOI: 10.3390/polym14040808 -
förtroende 1,0
“The IR band at 845 shows the Leal et al.”
Fernando 等 - 2017 - FTIR characterization and antioxidant activity of DOI: 10.4490/algae.2017.32.12.1 -
C c single bond förtroende 1,0
“cm-1 C-C C-O 1140 is due to the stretching of the and groups [53,54], the 1092 signal corresponds cm-1 C-O to the stretching of the group and the 845 stretch vibration corresponds to the C-C [54].”
Judith Valdez-Alegria 等 - 2020 - Synthesis of Chitosan-Polyvinyl Alcohol Biopolymer DOI: 10.3390/biom10010156
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