What absorbs at 662 cm⁻¹ in an FTIR spectrum?
A band near 662 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 8 cited sources
Brzi odgovor
A band near 662 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
Moguće dodjele funkcionalnih skupina
| Funkcionalna skupina | Potporni dokazi | Citirani izvori | Najveća pouzdanost |
|---|---|---|---|
| C-O single bond | 3 | 3 | 1,0 |
| Phosphate (PO4) | 1 | 1 | 1,0 |
| Methoxy (OCH3) | 1 | 1 | 1,0 |
| Methacrylate | 1 | 1 | 1,0 |
| Acetate | 1 | 1 | 1,0 |
| Hydroxyl (O-H) | 1 | 1 | 1,0 |
| Aromatic ring | 1 | 1 | 1,0 |
| Ring structure | 1 | 1 | 1,0 |
| Secondary amine | 1 | 1 | 1,0 |
| C n single bond | 1 | 1 | 1,0 |
| Amide | 1 | 1 | 1,0 |
| Metal oxygen | 1 | 1 | 1,0 |
Rangiranje odražava akumulirane literaturne dokaze, a ne jedno autoritativno pravilo. Uvijek provjerite u kontekstu vašeg uzorka.
Mogući materijali
| Materijal | Potporni vrhovi | Preklapajuće skupine | Citirani izvori |
|---|---|---|---|
| cellulose | 662, 1735, 1650 | Methacrylate, C-O single bond, Methoxy (OCH3) | 1 |
| collagen | 662, 1408, 1660 | Methacrylate, Methoxy (OCH3), C-O single bond | 1 |
Materijali su prikazani samo kada ista literatura podržava ovu traku i barem jedan dodatni karakteristični vrh.
Logika spektra
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 662 cm⁻¹ is usually not enough for material identification by itself.
Upotreba u stvarnom svijetu
Ova vrsta upita uobičajena je u identifikaciji polimera, probiru nepoznate plastike, rješavanju problema u kontroli kvalitete, provjeri recikliranog materijala i pregledu dodjele vrhova potkrijepljenom literaturom.
Uobičajene pogreške
- Tretiranje jedne izolirane vrpce kao dokaza materijala bez provjere barem jednog ili dva podržavajuća pika.
- Zanemarivanje preklapanja: više funkcionalnih skupina može doprinositi u blizini istog valnog broja.
- Preskakanje validacije kada aditivi, mješavine, oksidacija ili kontaminacija mogu izobličiti spektar.
Savjet za provjeru
Kada nejasnoća ostane, validirajte hipotezu pomoću DSC, GC-MS ili TGA, posebno za mješavine, degradirane uzorke i punjene polimere.
Literatura iza ovih dodjela
-
Metal oxygen pouzdanost 1,0
“FTIR spectrum cm(cid:1)1 of SnQ shows band at 662 and a strong one at 564 which are Sn-O Sn-OH due to stretching and respectively [39,40].”
Shajira 等 - 2015 - Sunlight assisted photodegradation by tin oxide qu DOI: 10.1016/j.jpcs.2015.09.003 -
Amide pouzdanost 1,0
“(ii) the band at 662 assigned to the combination of stability.38 chemical behavior and In particular, NaBF was used ν(C-N) and δ ring modes;”
Dani 等 - 2015 - Design of high surface area poly(ionic liquid)s to DOI: 10.1039/c5ta00272a -
C-O single bond pouzdanost 1,0
“The band approximately at 662cm-1 mately at referred to the C-OH of plane bending mode.”
Investigate the role of fungal communities associated with a historical manuscript from the 17th century in biodegradation DOI: 10.1038/s41529-022-00296-4 -
Aromatic ring pouzdanost 1,0
“The band around 662 cm-1 may be assigned to the -CHbonding of aromatic groups [32].”
Impact and Tensile Properties of Polyester Nanocomposites Reinforced with Conifer Fiber Cellulose Nanocrystal:A Previous Study Extension DOI: 10.3390/polym13111878 -
C-O single bond pouzdanost 1,0
“The little peaks at approximately 662 C-OH bending (Fan et al.”
Chemical functional groups of extractives, cellulose and lignin extracted from native Leucaena leucocephala bark DOI: 10.1007/s00226-020-01258-2 -
Acetate pouzdanost 1,0
“sorption, the weak peaks at wavenumber 662 cm-1 (the expected bond is O 1CO 2), after CO 2 cm-1 cm-1 C-O+C···O), strong peaks at wavenumber 1007 (the expected bond is 1402 (the and 840 cm-1 (the expected bond is CO 3) are attributed to carb”
CO2 Sorption and Regeneration Properties of K2CO3/Al2O3-Based Sorbent at High Pressure and Moderate Temperature DOI: 10.3390/app12062989 -
Phosphate (PO4) pouzdanost 1,0
“In the spectrum of BG: P-O wagging is centered at 456 and P-O scissoring is centered at 662 cm-1 cm-1.”
Molecular and biological activities of metal oxide-modified bioactive glass DOI: 10.1038/s41598-023-37017-z -
pouzdanost 0,9
“Explicit assignment: 'and to maghemite (662 cm-1)'”
Desferrioxamine B: Investigating the Efficacy of Hydrogels and Ethanol Gels for Removing Akaganeite and Maghemite from Dry Wooden Substrates DOI: 10.3390/f14020247
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