What absorbs at 558 cm⁻¹ in an FTIR spectrum?
A band near 558 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 8 cited sources
Réponse rapide
A band near 558 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
Attributions possibles de groupes fonctionnels
| Groupe fonctionnel | Faits à l＇appui | Sources citées | Confiance maximale |
|---|---|---|---|
| Metal oxygen | 4 | 4 | 1,0 |
| Alkyl C-H | 2 | 2 | 1,0 |
| Amide | 2 | 2 | 1,0 |
| Phosphate (PO4) | 2 | 2 | 1,0 |
| Aromatic ring | 1 | 1 | 1,0 |
| Secondary amine | 1 | 1 | 1,0 |
| C n single bond | 1 | 1 | 1,0 |
| S s | 1 | 1 | 1,0 |
| C c single bond | 1 | 1 | 1,0 |
Le classement reflète les preuves bibliographiques accumulées, et non une règle faisant autorité. Confirmez toujours dans le contexte de votre échantillon.
Matériaux possibles
| Matériel | Pics de support | Groupes chevauchants | Sources citées |
|---|---|---|---|
| Zinc Oxide | 558, 1627, 1638 | Metal oxygen, Alkyl C-H, Amide | 1 |
| chitosan | 558, 1650, 1655 | Alkyl C-H, Amide | 1 |
| silver nanoparticles | 558, 1636, 1631 | Alkyl C-H, Amide | 1 |
| cotton fabric | 558, 900, 862 | Alkyl C-H, Amide | 1 |
Les matériaux sont affichés uniquement lorsque le même ensemble de littérature soutient cette bande et au moins un pic caractéristique supplémentaire.
Logique du spectre
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 558 cm⁻¹ is usually not enough for material identification by itself.
Utilisation réelle
Ce type de requête est courant dans l＇identification des polymères, le criblage des plastiques inconnus, le dépannage du contrôle qualité, la vérification des matériaux recyclés et l＇examen de l＇attribution des pics appuyée par la littérature.
Erreurs courantes
- Traiter une bande isolée comme preuve d＇un matériau sans vérifier au moins un ou deux pics de support.
- Ignorer le chevauchement : plusieurs groupes fonctionnels peuvent contribuer près du même nombre d＇onde.
- Sauter la validation lorsque des additifs, des mélanges, l＇oxydation ou la contamination peuvent déformer le spectre.
Conseil de vérification
Lorsque l＇ambiguïté persiste, validez l＇hypothèse avec DSC, GC-MS ou TGA, en particulier pour les mélanges, les échantillons dégradés et les polymères chargés.
Bibliographie derrière ces attributions
-
confiance 1,0
“The band at 558 in the parent at 558 and 435 cm-1 sample LaFeO is attributed to the Fe-O stretching vibration and the band at 435 correspond to the”
Rai 和 Thakur - 2017 - Effect of co-substitution on structural, optical, DOI: 10.1016/j.jallcom.2016.11.407 -
confiance 1,0
“The characteristic Fourier transform infrared spectrometal-oxygen scopy (FTIR) bands appeared at 658 and 558 cm-1 revealed the spinel-type crystal structure.”
Hydrothermal synthesis of spherical NiCO2O4 nanoparticles as a positive electrode for pseudocapacitor applications DOI: 10.1007/s10971-017-4504-y -
Metal oxygen confiance 1,0
“RHE, two The reduction of ammonia exhibited a similar trend under different cm-1 cm-1, and 558 belonging to Ni-O peaks began to appear at 479 initialconcentrationandtheremovalrateofammoniagraduallyslowed vibrations of NiOOH (Fig.”
Ni(II)/Ni(III) redox couple endows Ni foam-supported Ni2P with excellent capability for direct ammonia oxidation DOI: 10.1016/j.cej.2020.126795 -
Phosphate (PO4) confiance 1,0
“The characteristic peaks of the PO43groups are TiO 2-Ag 3PO 4 present at 1010 cm-1 and 558 cm-1 corresponding to P-O stretching vibrations [44,45].”
Hamrouni 等 - 2020 - Enhanced Solar Light Photocatalytic Activity of Ag DOI: 10.3390/nano10040795 -
Metal oxygen confiance 1,0
“A new peak at 776 assigned to the Mn-O bond was found in cm-1 MnDBC, F 1M 3DBC, and F 3M 1DBC, while a new peak at 558 belonging to the Fe-O bond was found in FDBC, F 1M 3DBC, and F 3M 1DBC, which illustrated the formation of Fe oxides, Mn”
Liang 等 - 2022 - Adsorption of Atrazine by Fe-Mn-Modified Biochar DOI: 10.3390/agronomy12123097 -
C c single bond confiance 1,0
“Also, a peak at 558 indicates cm-1 the (C-C) alkane stretching.”
Mondal 等 - 2023 - Recycling of silver nanoparticles from electronic DOI: 10.1038/s41598-023-40668-7 -
S s confiance 1,0
“The amide II peak becomes and is not a The absorption peak at 558 cm-1 defined S-S signal, evolving into a shoulder whose contribution corresponds to the bond associated with the”
Salinas Dominguez 等 - 2020 - Antibody Immobilization in Zinc Oxide Thin Films a DOI: 10.1021/acsomega.0c02583 -
Amide confiance 1,0
“558cm-1 2852cm-1 (Fe=O), 2921 and (Ccles, which are at 2𝜃/(∘) H,stretchingvibration),1455and1375cm-1 (C-N,stretching”
Sun 等 - 2017 - Activity and Stability of Trypsin Immobilized onto DOI: 10.1155/2017/1457072
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