What absorbs at 445 cm⁻¹ in an FTIR spectrum?

快速回答

A band near 445 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.

可能的官能基指派

排名反映累積的文獻證據，而非單一權威規則。請務必根據您的樣品背景進行確認。

可能的材料

僅當同一文獻庫支援此波段以及至少一個額外特徵峰時，才會顯示材料。

光譜邏輯

This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 445 cm⁻¹ is usually not enough for material identification by itself.

實際使用

此類查詢常見於聚合物鑑別、未知塑膠篩選、品管故障排除、再生材料驗證，以及基於文獻的峰值歸屬審查。

常見錯誤

• 將一個孤立的譜帶視為材料的證據，而未檢查至少一兩個支持峰。
• 忽略重疊：多個官能團可能在相同波數附近貢獻。
• 當添加劑、混合物、氧化或污染物可能扭曲譜圖時，跳過驗證。

驗證建議

當仍然存在歧義時，使用DSC、GC-MS或TGA驗證假設，特別是對於混合物、降解樣品和填充聚合物。

這些指派背後的文獻

• Carbonyl (C=O) 信心 1.0

  “443 The FTIR results for the black paint confirmed the presence of the characteristic absorption 444 peaks of an alkyd paint, dominated by the sharp and intense absorptions at 1720 and 1256 445 cm-1, due to the stretching mode of the carbon”

  Catto 等 - 2021 - Bioremoval of graffiti using novel commercial stra DOI: 10.1111/j.1574-6941.2006.00028.x
• Phosphate (PO4) 信心 1.0

  “Therefore, in the obtained Raman spectra the presence of the phosphate group is highlighted by the vibrational bands at around 445 and 432 cm-1 that could be attributed 𝜈 to (PO43-) bending mode.”

  Development of Silver Doped Hydroxyapatite Thin Films for Biomedical Applications DOI: 10.3390/coatings12030341
• 信心 1.0

  “445 asymmetric stretching vibration of the Si-O-T group between 991 and 977 446 Furthermore, when these bands are compared to the same band in the infrared spectra 447 of the precursors, MK and SSA, there is a shift of this band to a lower”

  Istuque 等 - 2019 - Effect of sewage sludge ash on mechanical and micr DOI: 10.1016/j.conbuildmat.2019.01.093
• 信心 1.0

  “The IR spectrum of pure ZnO particles cm-1 (Figure 5a) showed two characteristic peaks: a broad and very weak peak at 3431 (Figure 5a) showed two characteristic peaks: a broad and very weak peak at 3431 cm-1 correcorresponding to the O-H st”

  Deposition of Zinc Oxide Coatings on Wood Surfaces Using the Solution Precursor Plasma Spraying Process DOI: 10.3390/coatings11020183
• Ester 信心 1.0

  “a group of bands at 1238, 1163, 1114 and 1099 obtained from the 445 cm-1 ester groups stretching vibrations (-C-O);”

  Kharbach 等 - 2021 - New insights into the Argan oil categories charact DOI: 10.1016/j.talanta.2020.122073
• Metal oxygen 信心 1.0

  “The two strong bands at 445 and 610 are attributed to the O-Ti-O bending vibration and asymmetric Ti-O stretching vibration, respectively.”

  In Situ High-Pressure Raman Spectroscopic, Single-Crystal X-ray Diffraction, and FTIR Investigations of Rutile and TiO2II DOI: 10.3390/min13050703
• Silicon (Si) 信心 1.0

  “cm-1 cm-1 υ2-type Two peaks at about 445 and 483 associated with internal deformaTwo peaks at about 445 cm-1 and 483 cm-1 associated with υ2-type internal υ4-type tions (O non-Si-O vibrations) and asymmetric bending (ASB) vibrations deforma”

  Madadi 和 Wei - 2022 - Characterization of Calcium Silicate Hydrate Gels DOI: 10.3390/gels8020075
• 信心 1.0

  “These DTG curves also presented peaks 445 related to the formation of hydrated calcium silicates and calcium aluminates.”

  Moraes 等 - 2019 - Production of bamboo leaf ash by auto-combustion f DOI: 10.1016/j.conbuildmat.2019.03.007