What absorbs at 549 cm⁻¹ in an FTIR spectrum?
A band near 549 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 8 cited sources
Quick answer
A band near 549 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
可能性のある官能基アサイン
| 官能基 | 裏付け事実 | 引用元 | 最高信頼度 |
|---|---|---|---|
| Metal oxygen | 3 | 3 | 1.0 |
| Methoxy (OCH3) | 1 | 1 | 1.0 |
| Methacrylate | 1 | 1 | 1.0 |
| C-O single bond | 1 | 1 | 1.0 |
| Acetate | 1 | 1 | 1.0 |
| Aromatic ring | 1 | 1 | 1.0 |
| Alkyl C-H | 1 | 1 | 1.0 |
ランキングは蓄積された文献証拠を反映しており、単一の権威あるルールではありません。常にサンプルのコンテキストと照合して確認してください。
Possible materials
| 素材 | 補助ピーク | Overlapping groups | 引用元 |
|---|---|---|---|
| silver nanoparticles | 549, 1636, 1631 | Methacrylate, C-O single bond, Methoxy (OCH3) | 1 |
Materials are shown only when the same literature pool supports this band and at least one additional characteristic peak.
Spectrum logic
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 549 cm⁻¹ is usually not enough for material identification by itself.
Real-world usage
This type of query is common in polymer identification, unknown plastic screening, QC troubleshooting, recycled-material verification, and literature-backed peak assignment review.
Common mistakes
- Treating one isolated band as proof of a material without checking at least one or two supporting peaks.
- Ignoring overlap: multiple functional groups can contribute near the same wavenumber.
- Skipping validation when additives, blends, oxidation, or contamination may distort the spectrum.
Verification advice
When ambiguity remains, validate the hypothesis with DSC, GC-MS, or TGA, especially for blends, degraded samples, and filled polymers.
これらのアサインの根拠となる文献
-
Alkyl C-H 信頼度 1.0
“Cthe spectra at 3keV with an atomic percentage of 55.32 indicates the presence of band at wavenumber 549 Previous studies have also reported that the nanoparticle size Br functional group belongs to alkyl halides.”
Biofabrication of silver nanoparticles from aqueous leaf extract of Leucas aspera and their anticancer activity on human cervical cancer cells DOI: 10.1088/2043-6254/ab5103 -
信頼度 1.0
“Text: 'vibration bands at around 549 and 1226 indicated the presence of double 5-ring in ZSM-5.'”
Synthesis of ZSM5 Zeolite Particles Using Triethanol Amine as StructureDirecting Agent DOI: 10.1111/j.1551-2916.2011.05006.x -
Metal oxygen 信頼度 1.0
“Cr O , nopeakof 2oranyotherstoichiometryofchromiumoxidewasfoundinthe CrO 2 3 investigation.TheRamanbandcentredat549cm-1isofA 1gmodesymmetry,whiletheshiftat304cm-1and 350cm-1areofE gsymmetry[16,17].”
Ogwu 等 - 2016 - Corrosion, ion release and Mott-Schottky probe of DOI: 10.1088/2053-1591/3/4/045401 -
Metal oxygen 信頼度 1.0
“437cm(cid:2)1and 598cm(cid:2)1 absorption bands at 549, are related to the vibrations of the metal-oxygen bond in octahedral and tetrahedral sites, respectively.”
Rasouli 等 - 2020 - Structural, magnetic, and microwave absorption pro DOI: 10.1080/08327823.2020.1714104 -
Aromatic ring 信頼度 1.0
“1A, 1E), both the 1,649 and and cm-1, cm-1, cm-1 1,516 1,496 (aromatic ring skeleton vibracm-1 absorption peaks appear simultaneously the 1,549 cm-1, cm-1 1,375 (C-H bending vibration), and tion), 1,472 in their spectra.”
Ch'ng 等 - 2016 - Vasorelaxation Study and Tri-Step Infrared Spectro DOI: 10.3831/KPI.2016.19.016 -
Acetate 信頼度 1.0
“Cells were cultured in T-75 conformational changes in both proteins and nucleic acids, as 80-90% flasks (Greiner, USA) and at confluence, they were C-O well as showed a higher band of carbohydrates in A549 sub-cultured in a 1:10 to 1:12 spl”
Guler 等 - 2019 - Characterization of CD133(+)CD44(+) human prostat DOI: 10.1039/c9an00093c -
信頼度 1.0
“bond between Mg and O shows a peak at 549 cm-1 Int.”
Lopez-Rodriguez 等 - 2023 - Dyeing with Hydrotalcite Hybrid Nanoclays and Disp DOI: 10.3390/ijms24010808 -
Metal oxygen 信頼度 0.9
“Explicit assignment in text.”
Velayutham 和 Selvapandiyan - 2019 - Effect of yttrium ion on the properties of tri eth DOI: 10.1016/j.heliyon.2019.e02091
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