What absorbs at 448 cm⁻¹ in an FTIR spectrum?
A band near 448 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 5 cited sources
快速回答
A band near 448 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
可能的官能基指派
| 官能基 | 支持事實 | 引用來源 | 最高信心 |
|---|---|---|---|
| Silicon-oxygen (Si-O) | 2 | 1 | 1.0 |
| Protein | 1 | 1 | 1.0 |
| Phosphorus | 1 | 1 | 1.0 |
| Phosphate (PO4) | 1 | 1 | 1.0 |
| Fatty acid | 1 | 1 | 1.0 |
| Ring structure | 1 | 1 | 1.0 |
| Siloxane (Si-O-Si) | 1 | 1 | 1.0 |
| Silicon (Si) | 1 | 1 | 1.0 |
| Methoxy (OCH3) | 1 | 1 | 1.0 |
| Methacrylate | 1 | 1 | 1.0 |
| C-O single bond | 1 | 1 | 1.0 |
| Acetate | 1 | 1 | 1.0 |
排名反映累積的文獻證據，而非單一權威規則。請務必根據您的樣品背景進行確認。
光譜邏輯
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 448 cm⁻¹ is usually not enough for material identification by itself.
實際使用
此類查詢常見於聚合物鑑別、未知塑膠篩選、品管故障排除、再生材料驗證，以及基於文獻的峰值歸屬審查。
常見錯誤
- 將一個孤立的譜帶視為材料的證據，而未檢查至少一兩個支持峰。
- 忽略重疊：多個官能團可能在相同波數附近貢獻。
- 當添加劑、混合物、氧化或污染物可能扭曲譜圖時，跳過驗證。
驗證建議
當仍然存在歧義時，使用DSC、GC-MS或TGA驗證假設，特別是對於混合物、降解樣品和填充聚合物。
這些指派背後的文獻
-
Acetate 信心 1.0
“increasedfrom300to500,700and900◦ C,onlyabroadbandof The peaks at 1683 and 1624 represents the C O and C O in 448cm-1, 1393cm-1 zinc oxide was observed (460, 465 and respectively) the spectrum [17].”
Wahab 等 - 2008 - Synthesis and characterization of hydrozincite and DOI: 10.1016/j.jallcom.2007.07.029 -
Silicon (Si) 信心 1.0
“The absorption peak around 448 corresponded to the Si-O-Si bending”
El Ouardi 等 - 2020 - An insight of enhanced natural material (calcined DOI: 10.1016/S0043-1354(01)00071-9 -
Ring structure 信心 1.0
“In FT-Raman Photoluminescence (PL) spectroscopy is one of the powerful tools to cm(cid:3)1 Spectrum, a peak observed at 448 is due to OBO ring bending.”
Structural, vibrational and optical studies on semiorganic crystals of boric acid potassium acetate DOI: 10.1016/j.heliyon.2019.e03133 -
Fatty acid 信心 1.0
“between 3029-2767 and 1785-400 The first region is attributed to stretching 448 vibrations (peroxides) and some variation in fatty acids content (secondary oxidation products).”
Kharbach 等 - 2021 - New insights into the Argan oil categories charact DOI: 10.1016/j.talanta.2020.122073 -
Phosphate (PO4) 信心 1.0
“For the comparison of the fluorescence intensities of aCRY•8-HDF, aCRY and 8-HDF solvated in phosphate buffer or DMSO samples were excited at their absorption maxima at 448, 447, 421 and 455 nm respectively, with a bandwidth of 5 nm and a d”
Oldemeyer 等 - 2020 - Interconnection of the Antenna Pigment 8-HDF and F DOI: 10.1021/acs.biochem.9b00875
有包含此波峰的圖譜嗎？
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