What absorbs at 2842 cm⁻¹ in an FTIR spectrum?
A band near 2842 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 3 cited sources
Quick answer
A band near 2842 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
Возможные назначения функциональных групп
| Функциональная группа | Подтверждающие факты | Цитируемые источники | Максимальная достоверность |
|---|---|---|---|
| Alkyl C-H | 2 | 2 | 1,0 |
| Methyl | 1 | 1 | 1,0 |
| Silicon hydride | 1 | 1 | 1,0 |
| Methoxy (OCH3) | 1 | 1 | 1,0 |
| Hydroxyl (O-H) | 1 | 1 | 1,0 |
Ранжирование отражает накопленные литературные данные, а не единственное авторитетное правило. Всегда проверяйте в контексте вашего образца.
Possible materials
| Материал | Поддерживающие пики | Overlapping groups | Цитируемые источники |
|---|---|---|---|
| clay | 2842, 1736, 2855 | Alkyl C-H | 1 |
Materials are shown only when the same literature pool supports this band and at least one additional characteristic peak.
Spectrum logic
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 2842 cm⁻¹ is usually not enough for material identification by itself.
Real-world usage
This type of query is common in polymer identification, unknown plastic screening, QC troubleshooting, recycled-material verification, and literature-backed peak assignment review.
Common mistakes
- Treating one isolated band as proof of a material without checking at least one or two supporting peaks.
- Ignoring overlap: multiple functional groups can contribute near the same wavenumber.
- Skipping validation when additives, blends, oxidation, or contamination may distort the spectrum.
Verification advice
When ambiguity remains, validate the hypothesis with DSC, GC-MS, or TGA, especially for blends, degraded samples, and filled polymers.
Литература, лежащая в основе этих назначений
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Hydroxyl (O-H) достоверность 1,0
“ACCEPTED MANUSCRIPT cm-1 band at 2842 and 1685 indicated the presence of -OH stretching of intramolecular hydrogen 237 bond, C=O stretching and C-H stretching of alkanes.”
Antibacterial, antibiofilm and cytotoxic effects of Nigella sativa essential oil coated gold nanoparticles DOI: 10.1016/j.micpath.2015.11.021 -
Alkyl C-H достоверность 1,0
“FT-IR of IBTMS, Ce (NO 3) 3, W 1, PS and MCs cm-1, As shown in Figure 1C, the spectrum of IBTMS has an absorption band of 2842 which is attributed to the (C-H) bonds stretching vibrations of methoxy groups (-OCH 3)”
Enhanced Coating Protection of C-Steel Using Polystyrene Clay Nanocomposite Impregnated with Inhibitors DOI: 10.3390/polym15020372 -
Methyl достоверность 1,0
“Text: 'methyl and methylene at ... 2842'”
Zhang 和 Zhou - 2022 - Industrial lignins the potential for efficient re DOI: 10.21203/rs.3.rs-453856/v1
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