What absorbs at 2368 cm⁻¹ in an FTIR spectrum?
A band near 2368 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 5 cited sources
快速回答
A band near 2368 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
可能的官能基指派
| 官能基 | 支持事實 | 引用來源 | 最高信心 |
|---|---|---|---|
| Methoxy (OCH3) | 1 | 1 | 1.0 |
| Methacrylate | 1 | 1 | 1.0 |
| C-O single bond | 1 | 1 | 1.0 |
| Acetate | 1 | 1 | 1.0 |
| C c single bond | 1 | 1 | 1.0 |
| Hydrogen bond | 1 | 1 | 1.0 |
| Hydroxyl (O-H) | 1 | 1 | 1.0 |
排名反映累積的文獻證據,而非單一權威規則。請務必根據您的樣品背景進行確認。
可能的材料
| 材料 | 支持峰 | 重疊基團 | 引用來源 |
|---|---|---|---|
| TiO2 | 2368, 1700, 1093 | Methacrylate, Acetate, C-O single bond | 1 |
| TiO | 2368, 1730, 1699 | Methacrylate, Acetate, Methoxy (OCH3) | 1 |
| TiO2 nanoparticles | 2368, 1700, 455 | Methacrylate, C-O single bond, Acetate | 1 |
僅當同一文獻庫支援此波段以及至少一個額外特徵峰時,才會顯示材料。
光譜邏輯
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 2368 cm⁻¹ is usually not enough for material identification by itself.
實際使用
此類查詢常見於聚合物鑑別、未知塑膠篩選、品管故障排除、再生材料驗證,以及基於文獻的峰值歸屬審查。
常見錯誤
- 將一個孤立的譜帶視為材料的證據,而未檢查至少一兩個支持峰。
- 忽略重疊:多個官能團可能在相同波數附近貢獻。
- 當添加劑、混合物、氧化或污染物可能扭曲譜圖時,跳過驗證。
驗證建議
當仍然存在歧義時,使用DSC、GC-MS或TGA驗證假設,特別是對於混合物、降解樣品和填充聚合物。
這些指派背後的文獻
-
Hydroxyl (O-H) 信心 1.0
“The peak at 1544 corresponds to the bending vibrations of N-H bond and 41 cm-1 the existence of peak at 2368 recognizes to asymmetric stretching vibrations of O-H bonds in free OH groups.”
Kaur 等 - 2019 - Expanding horizon green synthesis of TiO2 nanopar DOI: 10.1088/2053-1591/ab2ec5 -
C c single bond 信心 1.0
“peak at 2368 indicates the presence of C (cid:7) Figure 5 shows the XRD spectrum corresponding to the N or C C stretching vibration.”
Green synthesis of bimetallic Pt@Cu nanostructures for catalytic oxidative desulfurization of model oil DOI: 10.1007/s40097-017-0223-8 -
信心 1.0
“2368.44cm-1 2323.25cm-1 that appeared at and indicate the made a significant alteration due to aggregation of GV presence of nitrogen linkage, which is present in the molecules on the surface of sorbent, which might reduce the structure of”
Akram 等 - 2021 - Kinetic and Isothermal Investigations of Cost-Effe DOI: 10.1155/2021/5549536 -
Acetate 信心 1.0
“oC, cm-1, spectrum of the sample sintered at 950 a small peak was observed at ~2368 which is commonly assigned to the vibration band of C-O [36], probably originated from atmospheric CO 2 adsorbed by the sample during its preparation.”
Sembiring 等 - 2014 - Synthesis and characterisation of gel-derived mull DOI: 10.1016/j.ceramint.2013.12.038 -
信心 0.9
“Explicit assignment: 'peak at 2368 as the amine group (N-H) of the protein'”
Khoironi 等 - 2023 - Impact of disposable mask microplastics pollution DOI: 10.1007/s11356-023-27651-5
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