What absorbs at 578 cm⁻¹ in an FTIR spectrum?
A band near 578 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 8 cited sources
Hiter odgovor
A band near 578 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
Možne dodelitve funkcionalnih skupin
| Funkcionalna skupina | Podporna dejstva | Citirani viri | Najvišje zaupanje |
|---|---|---|---|
| Alkyl C-H | 2 | 2 | 1,0 |
| Hydroxyl (O-H) | 1 | 1 | 1,0 |
| Silicon (Si) | 1 | 1 | 1,0 |
| Siloxane (Si-O-Si) | 1 | 1 | 1,0 |
| Silicon-oxygen (Si-O) | 1 | 1 | 1,0 |
| Alkene (C=C) | 1 | 1 | 1,0 |
| Metal oxygen | 1 | 1 | 0,9 |
| Carboxyl (COOH) | 1 | 1 | 0,9 |
| Phosphate (PO4) | 1 | 1 | 0,8 |
Razvrstitev odraža zbrane literaturne dokaze, ne enega avtoritativnega pravila. Vedno preverite glede na kontekst vašega vzorca.
Možni materiali
| Material | Podporni vrhovi | Prekrivajoče se skupine | Citirani viri |
|---|---|---|---|
| SiO2 | 578, 1739, 699 | Alkyl C-H, Silicon (Si), Hydroxyl (O-H) | 1 |
| CuO | 578, 453, 1000 | Hydroxyl (O-H) | 1 |
| Fe2O3 | 578, 1130, 1631 | Hydroxyl (O-H), Alkyl C-H | 1 |
| PVC | 578, 834, 1195 | Alkyl C-H, Hydroxyl (O-H) | 1 |
Materiali so prikazani le, ko ista literaturna podlaga podpira ta pas in vsaj en dodatni karakteristični vrh.
Logika spektra
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 578 cm⁻¹ is usually not enough for material identification by itself.
Uporaba v resničnem svetu
Ta vrsta poizvedbe je pogosta pri identifikaciji polimerov, pregledovanju neznanih plastičnih mas, odpravljanju težav pri QC, preverjanju recikliranih materialov in literaturno podprtem pregledu dodelitev vrhov.
Pogoste napake
- Obravnavanje enega izoliranega pasu kot dokaza o materialu brez preverjanja vsaj enega ali dveh podpornih vrhov.
- Ignoriranje prekrivanja: več funkcionalnih skupin lahko prispeva blizu istega valovnega števila.
- Izpuščanje validacije, ko lahko dodatki, mešanice, oksidacija ali kontaminacija popačijo spekter.
Nasvet za preverjanje
Ko ostaja dvoumnost, potrdite hipotezo z DSC, GC-MS ali TGA, zlasti za mešanice, degradirane vzorce in polnjene polimere.
Literatura za temi dodelitvami
-
zaupanje 1,0
“The bands at 475 was ascribed to CuO cm-1 Fe3+ O2vibration, whereas that at 578 corresponding to the and bonds stretching in the FeO 4 Page 5/33 tetrahedron (Hao et al.”
Bousalah 等 - 2022 - Enhanced reactivity of the CuO-Fe2O3 intimate hete DOI: 10.21203/rs.3.rs-1276158/v1 -
Alkene (C=C) zaupanje 1,0
“The -CH=CH2 characteristic absorption peak -CH=CH stretching vibration peak of Fe-Ois 578 The characteristic absorption 2 cm-1 at 1630 cm-1 of the synthesized monomer GMA disappeared after the preparation of the peak at 1630 of the synthesi”
Design and Preparation of Imidazole Ionic Liquid-Based Magnetic Polymers and Its Adsorption on Sunset Yellow Dye DOI: 10.3390/ma15072628 -
zaupanje 1,0
“Si or Al, symmetric stretching vibration of CO at about 2 cm-1, 873 symmetrically stretching vibration of Si-O at 698 cm-1,bendingvibrationofSi-O-Alat578cm-1 andin-plane cm-1 bending vibration of Si-O-Si and O-Si-O at 453 respectively as in”
Meng 等 - 2021 - Effects of load types and critical molar ratios on DOI: 10.1515/rams-2021-0019 -
Silicon (Si) zaupanje 1,0
“The Si2843 777 2922 1146 2978 1032 3753 3461 578 cm-1 O-Si bending mode appears at 446 (435) [49].”
Rangelova 等 - 2011 - MethylcelluloseSiO2 hybrids sol-gel preparation DOI: 10.2478/s11532-010-0123-y -
Hydroxyl (O-H) zaupanje 1,0
“2 cm-1 cm-1 obtained for the data acquired from DSC or FTIR 681.8 (C-Cl stretching), 577.6 (O-H bending (Table 2).”
Principal component and cluster analyses as supporting tools for co-crystals detection DOI: 10.1007/s10973-017-6436-8 -
Alkyl C-H zaupanje 1,0
“The correlation and (c), the FITR and NMR bands were strongly correlated with intensities of aromatic carbons with other factors were much XPS band at 577.6 eV that represents the signal of reduced higher than that of aliphatic carbons, whi”
A novel method of three-dimensional hetero-spectral correlation analysis for the fingerprint identification of humic acid functional groups for hexavalent chromium retention DOI: 10.1039/c7ra12146f -
Carboxyl (COOH) zaupanje 0,9
“Explicit assignment in text.”
Jonynaite 等 - 2010 - Spectroscopic analysis of blue cobalt smalt pigmen DOI: 10.1016/j.vibspec.2009.12.005 -
zaupanje 0,9
“Text: 'as(CF3) ... peaks at ... 578'”
Ramesh 和 Yi - 2009 - FTIR spectra of plasticized high molecular weight DOI: 10.1007/s11581-008-0279-z
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