What absorbs at 488 cm⁻¹ in an FTIR spectrum?
A band near 488 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 7 cited sources
快速回答
A band near 488 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
可能的官能基指派
| 官能基 | 支持事實 | 引用來源 | 最高信心 |
|---|---|---|---|
| Metal oxygen | 2 | 2 | 1.0 |
| Phosphate (PO4) | 1 | 1 | 1.0 |
| Carboxyl (COOH) | 1 | 1 | 1.0 |
| Silicon-oxygen (Si-O) | 1 | 1 | 1.0 |
| Hydroxyl (O-H) | 1 | 1 | 1.0 |
排名反映累積的文獻證據,而非單一權威規則。請務必根據您的樣品背景進行確認。
光譜邏輯
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 488 cm⁻¹ is usually not enough for material identification by itself.
實際使用
此類查詢常見於聚合物鑑別、未知塑膠篩選、品管故障排除、再生材料驗證,以及基於文獻的峰值歸屬審查。
常見錯誤
- 將一個孤立的譜帶視為材料的證據,而未檢查至少一兩個支持峰。
- 忽略重疊:多個官能團可能在相同波數附近貢獻。
- 當添加劑、混合物、氧化或污染物可能扭曲譜圖時,跳過驗證。
驗證建議
當仍然存在歧義時,使用DSC、GC-MS或TGA驗證假設,特別是對於混合物、降解樣品和填充聚合物。
這些指派背後的文獻
-
信心 1.0
“peak at ~488 due to Zn-O stretching mode.”
Chakraborty 等 - 2012 - ZnOTi Thin Film Synthesis, Characterization and DOI: 10.1088/1742-6596/390/1/012065 -
Hydroxyl (O-H) 信心 1.0
“The Mn doping has in900 which correspond to strain vibration of O-H group of duced a change of particle shape, from the typical rod-like one 900 which correspond to strain vibration of O-H group of duced a change of particle shape, from the”
Harsono 等 - 2017 - Paramagnetic Zn(1-x)MnxO (0.00≤x≤0.06) Nanopar DOI: 10.4313/TEEM.2017.18.1.46 -
信心 1.0
“Vibrations(cm-1) Assignment 488 Si O SirockingvibrationinLOmode 522 LowerfrequencySi Ovibration”
Jana 等 - 2008 - Non-hydrolytic sol-gel synthesis of epoxysilane-ba DOI: 10.1016/j.matchemphys.2008.06.070 -
Carboxyl (COOH) 信心 1.0
“The equivalent carboxyl group peaks in 488 (1:100) U.K.) in 1% BSA in PBS, was cm-1, respectively18 pure Tar are observed at 1550 and 1740 consequently added to the samples and incubated for 1 h at room confirms temperature followed by anot”
Chiral Tartaric Acid Improves Fracture Toughness of Bioactive Brushite–Collagen Bone Cements DOI: 10.1021/acsabm.0c00555 -
Phosphate (PO4) 信心 1.0
“The strong adsorption band at around 1125 cm-1 was ascribed to an asymmetric P-O-Al stretching vibration, and the one at 488 cm-1 was assigned to symmetrical P-O-Al deformation vibration [38,39];”
Efficient and Stable O-Methylation of Catechol with Dimethyl Carbonate over Aluminophosphate Catalysts DOI: 10.3390/catal13010150 -
信心 0.9
“Explicit assignment in text.”
Magnetic Properties of MFeCrO4 (M = Co/Ni) Prepared by Solution Combustion Method DOI: 10.1007/s10948-019-5080-x -
信心 0.8
“Assigned to ν(Sn-O) in region 488-495”
Tributyltin(IV) Butyrate: A Novel Epigenetic Modifier with ER Stress- and Apoptosis-Inducing Properties in Colon Cancer Cells DOI: 10.3390/molecules26165010
有包含此波峰的圖譜嗎?
上傳您的FTIR圖譜,幾秒內即可獲得完整的解讀報告——包含帶有文獻引用的峰位指派、圖譜庫比對以及信心等級評估的證據鏈。