What absorbs at 477 cm⁻¹ in an FTIR spectrum?
A band near 477 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 6 cited sources
Quick answer
A band near 477 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
Iespējamie funkcionālo grupu piešķīrumi
| Funkcionālā grupa | Atbalstošie fakti | Citētie avoti | Augstākā pārliecība |
|---|---|---|---|
| Metal oxygen | 2 | 2 | 1,0 |
| Carbohydrate | 1 | 1 | 1,0 |
| Alkyl C-H | 1 | 1 | 1,0 |
| Silicon-oxygen (Si-O) | 1 | 1 | 1,0 |
| Nucleic acid | 1 | 1 | 1,0 |
| Hydroxyl (O-H) | 1 | 1 | 1,0 |
Rangs atspoguļo uzkrātos literatūras pierādījumus, nevis vienu autoritatīvu noteikumu. Vienmēr apstipriniet atbilstoši parauga kontekstam.
Possible materials
| Materiāls | Atbalstošie pīķi | Overlapping groups | Citētie avoti |
|---|---|---|---|
| Silica nanoparticles | 477, 1718, 2925 | Silicon-oxygen (Si-O), Alkyl C-H | 1 |
Materials are shown only when the same literature pool supports this band and at least one additional characteristic peak.
Spectrum logic
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 477 cm⁻¹ is usually not enough for material identification by itself.
Real-world usage
This type of query is common in polymer identification, unknown plastic screening, QC troubleshooting, recycled-material verification, and literature-backed peak assignment review.
Common mistakes
- Treating one isolated band as proof of a material without checking at least one or two supporting peaks.
- Ignoring overlap: multiple functional groups can contribute near the same wavenumber.
- Skipping validation when additives, blends, oxidation, or contamination may distort the spectrum.
Verification advice
When ambiguity remains, validate the hypothesis with DSC, GC-MS, or TGA, especially for blends, degraded samples, and filled polymers.
Literatūra aiz šiem piešķīrumiem
-
Metal oxygen pārliecība 1,0
“The first band band position is due to the difference in the discm-1 at 477.25 represents the vibration due to metal-oxygen tances for the octahedral and tetrahedral complexes.”
Influence of cobalt substitution on structural, optical, electrical and magnetic properties of nanosized lithium ferrite DOI: 10.1007/s10854-018-9744-2 -
pārliecība 1,0
“The cm-1 cm-1 peak observed at 477 and 620 can be assigned Experimental Fish and Acclimatization: The work was to Ni-O and Ni-O-H bond, respectively.”
Aziz 等 - 2021 - Effect of Engineered Nickel Oxide Nanoparticles on DOI: 10.29261/pakvetj/2021.044 -
Nucleic acid pārliecība 1,0
“The Raman spectrum of DNA TFs exhibited 6 O TiO 2] in the DNA and DNA-CT TFs increased due to the characteristic Raman bands centered at around 477, 678, 732, cto physical interactions between them.”
Dugasani 等 - 2019 - Optoelectronic properties of DNA thin films implan DOI: 10.1063/1.5063446 -
pārliecība 1,0
“SiO 2-NPs were suspended in saline solution, spectral bands detected were 477 for Si-O out of cm-1 cm-1 cm-1 plane deformation, 801 for Si-O bending, 970 for Si-OH stretching, 1097 for Si-O-Si asymmetric stretching (Figure 1b).”
Astrocytes Are More Vulnerable than Neurons to Silicon Dioxide Nanoparticle Toxicity in Vitro DOI: 10.3390/toxics8030051 -
Alkyl C-H pārliecība 1,0
“bending vibration bands were recognized at 601 and 477cm-1 The stretching mode energy responds to variations in unit [35], the bending of C-H was observed at 875 cm-1 cell volume via two mechanisms: shifts in bond length and [36].”
Ismail 等 - 2023 - The role of nanoparticles inclusion in monitoring DOI: 10.1007/s41779-023-00836-4 -
Carbohydrate pārliecība 1,0
“LLM confirmed rule peak-group candidate”
Vibrational and fluorescence spectroscopy to study gluten and zein interactions in complex dough systems DOI: 10.1016/j.crfs.2022.02.009
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