What absorbs at 466 cm⁻¹ in an FTIR spectrum?
A band near 466 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 8 cited sources
Përgjigje e shpejtë
A band near 466 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
Caktime të mundshme të grupeve funksionale
| Grup funksional | Fakte mbështetëse | Burimet e cituara | Besueshmëri e lartë |
|---|---|---|---|
| Silicon-oxygen (Si-O) | 9 | 8 | 1,0 |
| Silicon (Si) | 4 | 4 | 1,0 |
| Siloxane (Si-O-Si) | 4 | 4 | 1,0 |
| Ring structure | 1 | 1 | 1,0 |
| Secondary amine | 1 | 1 | 1,0 |
| C n single bond | 1 | 1 | 1,0 |
| Amide | 1 | 1 | 1,0 |
| Alkyl C-H | 1 | 1 | 1,0 |
| Hydroxyl (O-H) | 1 | 1 | 1,0 |
| Metal oxygen | 1 | 1 | 0,9 |
Renditja pasqyron provat e grumbulluara të literaturës, jo një rregull të vetëm autoritar. Gjithmonë konfirmoni në kontekstin e mostrës suaj.
Materialet e mundshme
| Material | Maja mbështetëse | Grupe të mbivendosura | Burimet e cituara |
|---|---|---|---|
| SiO2 | 466, 1739, 699 | Silicon-oxygen (Si-O), Silicon (Si), Siloxane (Si-O-Si) | 2 |
| Silica | 466, 1100, 1080 | Silicon-oxygen (Si-O), Silicon (Si), Siloxane (Si-O-Si) | 1 |
Materialet shfaqen vetëm kur i njëjti grup literature mbështet këtë brez dhe të paktën një pik karakteristik shtesë.
Logjika e spektrit
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 466 cm⁻¹ is usually not enough for material identification by itself.
Përdorimi në botën reale
Ky lloj pyetjeje është i zakonshëm në identifikimin e polimereve, skriningun e plastikës së panjohur, zgjidhjen e problemeve të kontrollit të cilësisë, verifikimin e materialeve të ricikluara dhe rishikimin e caktimit të pikut të mbështetur nga literatura.
Gabimet e zakonshme
- Trajtimi i një brezi të izoluar si provë e një materiali pa kontrolluar të paktën një ose dy pika mbështetëse.
- Duke injoruar mbivendosjen: grupe të shumta funksionale mund të kontribuojnë afër të njëjtit numër valor.
- Kalimi i vërtetimit kur aditivët, përzierjet, oksidimi ose ndotja mund të shtrembërojnë spektrin.
Këshillë për verifikim
Kur mbetet paqartësi, verifiko hipotezën me DSC, GC-MS ose TGA, veçanërisht për përzierjet, mostrat e degraduara dhe polimerët e mbushur.
Literatura pas këtyre caktimeve
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besueshmëri 1,0
“The [18] located the spectra region at 466 cm-1 and attributed it to the Ti-C vibration.”
Effect of Microstructural and Tribological Behaviors of Sputtered Titanium Carbide Thin Film on Copper Substrate DOI: 10.3390/ma16010174 -
Hydroxyl (O-H) besueshmëri 1,0
“465 PC1, PCB1), (P, PC2, PCB2), (P, PC3, PCB3) and (P, OPS, MRP, RF) predominantly showed 466 characteristic peaks of vibrationally active chemical groups those likely corresponding to hydroxyl USC (cm-1).”
Evaluation of structural integrity and functionality of commercial pectin based edible films incorporated with corn flour, beetroot, orange peel, muesli and rice flour DOI: 10.1016/j.foodhyd.2019.01.022 -
Silicon (Si) besueshmëri 1,0
“The absorption bands of RHA at cm-1 cm-1 466 is ascribed to Si-O distortion, 800 corresponds to Si-O bending, and Si-O-Si stretching appeared cm23.”
Rice husk derived Aminated Silica for the efficient adsorption of different gases DOI: 10.1038/s41598-020-76460-0 -
besueshmëri 1,0
“The absorption peak at 795 was documented in the Si-O-Si group, cm-1 and the detected peak was 466 in the Si-O-Si group [51,52].”
Sustainable Remedy Waste to Generate SiO2 Functionalized on Graphene Oxide for Removal of U(VI) Ions DOI: 10.3390/su14052699 -
Silicon-oxygen (Si-O) besueshmëri 1,0
“The absorption bands at 1097, 1037, 802 and 774 on cm-1 the IR spectra of RHA and WG are assigned to the O-Si-O in the SiO tetrahedron and the band at 466 is”
Lancellotti 等 - 2015 - Geopolymers An option for the valorization of inc DOI: 10.1016/j.ceramint.2014.10.008 -
Silicon-oxygen (Si-O) besueshmëri 1,0
“The bands at around 466 cm-1 for FA-1 and FA-2 are connected with the bending vibrations of O-Si-O present in the silicate tetrahedron [31].”
Structural Characterizations of Aluminosilicates in Two Types of Fly Ash Samples from Shanxi Province, North China DOI: 10.3390/min9060358 -
besueshmëri 1,0
“The Al-O-Si bending band appeared at 520 cm-1 and Si-O-Si bending at 466 cm-1 [63].”
The Antimicrobial Properties of Modified Pharmaceutical Bentonite with Zinc and Copper DOI: 10.3390/pharmaceutics13081190 -
besueshmëri 1,0
“For the test sample, unlike the samples from the calibration set, the Si-O (SiO 2) strain cm-1 vibration absorption band at 466 was noted, which also corresponds to a relatively”
Identification of the Elemental Composition of Granulated Blast Furnace Slag by FTIR-Spectroscopy and Chemometrics DOI: 10.3390/pr10112166
Keni një spektër me këtë brez?
Ngarkoni spektrin tuaj FTIR dhe merrni një raport të plotë interpretimi — caktim i pikut me citime literaturë, përputhje biblioteke dhe një zinxhir provash të vlerësuar me besueshmëri — në sekonda.