What absorbs at 401 cm⁻¹ in an FTIR spectrum?
A band near 401 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 7 cited sources
त्वरित उत्तर
A band near 401 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
संभाव्य कार्यात्मक-गट नियुक्त्या
| कार्यात्मक गट | समर्थन करणारी तथ्ये | उद्धृत स्रोत | सर्वोच्च आत्मविश्वास |
|---|---|---|---|
| N h | 5 | 5 | 1.0 |
| Secondary amine | 4 | 4 | 1.0 |
| N-O bond | 2 | 1 | 1.0 |
| C n single bond | 1 | 1 | 1.0 |
| Amide | 1 | 1 | 1.0 |
| Metal oxygen | 1 | 1 | 1.0 |
| Ammonium | 1 | 1 | 1.0 |
| Carbohydrate | 1 | 0 | 1.0 |
| Hydroxyl (O-H) | 1 | 0 | 1.0 |
| N n bond | 1 | 0 | 1.0 |
रँकिंग संचित साहित्य पुरावा प्रतिबिंबित करते, एकच अधिकृत नियम नाही. नेहमी तुमच्या नमुना संदर्भाविरुद्ध पुष्टी करा.
संभाव्य साहित्य
साहित्य केवळ तेव्हाच दर्शविले जातात जेव्हा समान साहित्य पूल या बँडला आणि किमान एक अतिरिक्त वैशिष्ट्यपूर्ण शिखराला समर्थन देतो.
स्पेक्ट्रम तर्क
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 401 cm⁻¹ is usually not enough for material identification by itself.
वास्तविक-जग वापर
या प्रकारचा प्रश्न पॉलिमर ओळख, अज्ञात प्लास्टिक स्क्रीनिंग, क्यूसी ट्रबलशूटिंग, रिसायकल केलेल्या सामग्रीची पडताळणी आणि साहित्य-समर्थित पीक असाइनमेंट पुनरावलोकनात सामान्य आहे.
सामान्य चुका
- कमीत कमी एक किंवा दोन सहाय्यक शिखरे तपासल्याशिवाय एका वेगळ्या बँडला सामग्रीचा पुरावा मानणे.
- ओव्हरलॅप दुर्लक्षित करणे: अनेक कार्यात्मक गट समान तरंगसंख्येजवळ योगदान देऊ शकतात.
- जेव्हा अॅडिटीव्हज, ब्लेंड्स, ऑक्सिडेशन किंवा दूषितता स्पेक्ट्रम विकृत करू शकतात तेव्हा वैधता वगळणे.
पडताळणी सल्ला
जेव्हा अस्पष्टता राहते, तेव्हा DSC, GC-MS किंवा TGA सह गृहीतक प्रमाणित करा, विशेषतः मिश्रण, खराब झालेले नमुने आणि भरलेले पॉलिमर यासाठी.
या नियुक्त्यांमागील साहित्य
-
N h आत्मविश्वास 1.0
“the peak at 401.2 4+ eV corresponds to NH in the APP.”
Liang 等 - 2020 - Thermal Kinetics of a Lignin-Based Flame Retardant DOI: 10.3390/polym12092123 -
आत्मविश्वास 1.0
“The weak peak at 401.1 eV is indicative of the presence of terminal amino functional group, originating from the incomplete”
Dual Roles of [NCN]2- on Anatase TiO2: A Fully Occupied Molecular Gap State for Direct Charge Injection into the Conduction Band and an Interfacial Mediator for the Covalent Formation of Heterostructured g-C3N4/a-TiO2 Nanocomposite DOI: 10.1016/j.apcatb.2020.119036 -
Ammonium आत्मविश्वास 1.0
“In this investigation, a novel compound characteristic peak at 401.36 eV corresponding to the -NH3?.”
Synthesis of a novel compound based on chitosan and ammonium polyphosphate for flame retardancy applications DOI: 10.1007/s10570-019-02671-y -
Metal oxygen आत्मविश्वास 1.0
“Figure 6b shows that the water contact 2 N-C 15.2° peaks at 400.7 eV were assigned to the bond, suggesting angle of APTMS-TiO 2@SiO was decreased to and that 2 126.2°”
Wang 等 - 2023 - Surface-Modified TiO2@SiO2 Nanocomposites for Enha DOI: 10.1021/acsomega.3c02679 -
आत्मविश्वास 1.0
“The peaks at 401.0 and 404.6 eV are attributed to the amino group (C-N-H) the graphitic N.”
Underlying Mechanisms of Reductive Amination on Pd-Catalysts: The Unique Role of Hydroxyl Group in Generating Sterically Hindered Amine DOI: 10.3390/ijms23147621 -
N h आत्मविश्वास 1.0
“In bonds), 400.43 (NH contrast, CoPc-immobilized GO showed the shifting of bands and a considerable intensity enhancement of the peak at 400.69 eV due to the electron-withdrawing effect of GO (Fig-”
Cobalt Phthalocyanine Immobilized on Graphene Oxide: An Efficient Visible-Active Catalyst for the Photoreduction of Carbon Dioxide DOI: 10.1002/chem.201304189 -
Secondary amine आत्मविश्वास 1.0
“BH (Figure For nylon 6-NH, vibrations of amide I and 401.0 eV attributed to the secondary amine and the new 3”
Yan 等 - 2022 - Functionalized Nylon 6 Fabric as an Efficient and DOI: 10.1021/acsomega.2c03401
या बँडसह स्पेक्ट्रम आहे का?
तुमचे FTIR स्पेक्ट्रम अपलोड करा आणि सेकंदात पूर्ण व्याख्या अहवाल मिळवा — साहित्य संदर्भांसह शिखर नियुक्त्या, लायब्ररी मॅचेस, आणि आत्मविश्वास-रेट केलेली पुरावा साखळी.