What absorbs at 401 cm⁻¹ in an FTIR spectrum?

Ateb cyflym

A band near 401 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.

Aseiniadau grŵp swyddogaethol posibl

Mae＇r safle＇n adlewyrchu tystiolaeth llenyddiaeth gronnwyd, nid rheol awdurdodol sengl. Cadarnhewch bob amser yn erbyn eich cyd-destun sampl.

Deunyddiau posibl

Mae deunyddiau＇n cael eu dangos dim ond pan fydd yr un gronfa lenyddiaeth yn cefnogi＇r band hwn ac o leiaf un brig nodweddiadol ychwanegol.

Rhesymeg sbectrwm

This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 401 cm⁻¹ is usually not enough for material identification by itself.

Defnydd yn y byd go iawn

Mae＇r math hwn o ymholiad yn gyffredin mewn adnabod polymer, sgrinio plastig anhysbys, datrys problemau QC, dilysu deunydd wedi＇i ailgylchu, ac adolygiad o aseiniad copa wedi＇i gefnogi gan lenyddiaeth.

Camgymeriadau cyffredin

• Trin un band ynysig fel prawf o ddeunydd heb wirio o leiaf un neu ddau gopa cefnogol.
• Anwybyddu gorgyffwrdd: gall grwpiau swyddogaethol lluosog gyfrannu ger yr un rhif ton.
• Hepgor dilysu pan fo ychwanegion, cymysgeddau, ocsideiddio, neu halogiad yn gallu ystumio＇r sbectrwm.

Cyngor dilysu

Pan fo amwysedd yn parhau, dilyswch y rhagdybiaeth gyda DSC, GC-MS, neu TGA, yn enwedig ar gyfer cymysgeddau, samplau dirywiedig, a pholymerau llawn.

Llenyddiaeth y tu ôl i＇r aseiniadau hyn

• N h hyder 1.0

  “the peak at 401.2 4+ eV corresponds to NH in the APP.”

  Liang 等 - 2020 - Thermal Kinetics of a Lignin-Based Flame Retardant DOI: 10.3390/polym12092123
• hyder 1.0

  “The weak peak at 401.1 eV is indicative of the presence of terminal amino functional group, originating from the incomplete”

  Dual Roles of [NCN]2- on Anatase TiO2: A Fully Occupied Molecular Gap State for Direct Charge Injection into the Conduction Band and an Interfacial Mediator for the Covalent Formation of Heterostructured g-C3N4/a-TiO2 Nanocomposite DOI: 10.1016/j.apcatb.2020.119036
• Ammonium hyder 1.0

  “In this investigation, a novel compound characteristic peak at 401.36 eV corresponding to the -NH3?.”

  Synthesis of a novel compound based on chitosan and ammonium polyphosphate for flame retardancy applications DOI: 10.1007/s10570-019-02671-y
• Metal oxygen hyder 1.0

  “Figure 6b shows that the water contact 2 N-C 15.2° peaks at 400.7 eV were assigned to the bond, suggesting angle of APTMS-TiO 2@SiO was decreased to and that 2 126.2°”

  Wang 等 - 2023 - Surface-Modified TiO2@SiO2 Nanocomposites for Enha DOI: 10.1021/acsomega.3c02679
• hyder 1.0

  “The peaks at 401.0 and 404.6 eV are attributed to the amino group (C-N-H) the graphitic N.”

  Underlying Mechanisms of Reductive Amination on Pd-Catalysts: The Unique Role of Hydroxyl Group in Generating Sterically Hindered Amine DOI: 10.3390/ijms23147621
• N h hyder 1.0

  “In bonds), 400.43 (NH contrast, CoPc-immobilized GO showed the shifting of bands and a considerable intensity enhancement of the peak at 400.69 eV due to the electron-withdrawing effect of GO (Fig-”

  Cobalt Phthalocyanine Immobilized on Graphene Oxide: An Efficient Visible-Active Catalyst for the Photoreduction of Carbon Dioxide DOI: 10.1002/chem.201304189
• Secondary amine hyder 1.0

  “BH (Figure For nylon 6-NH, vibrations of amide I and 401.0 eV attributed to the secondary amine and the new 3”

  Yan 等 - 2022 - Functionalized Nylon 6 Fabric as an Efficient and DOI: 10.1021/acsomega.2c03401