What absorbs at 601 cm⁻¹ in an FTIR spectrum?
A band near 601 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 8 cited sources
Quick answer
A band near 601 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
가능한 작용기 할당
| 작용기 | 지원 사실 | 인용 출처 | 최고 신뢰도 |
|---|---|---|---|
| Phosphate (PO4) | 6 | 6 | 1.0 |
| Metal oxygen | 3 | 3 | 1.0 |
| Phosphorus | 2 | 2 | 1.0 |
| Alkyl C-H | 1 | 1 | 1.0 |
| Carbonate | 1 | 1 | 0.7 |
순위는 단일 권위 규칙이 아닌 축적된 문헌 증거를 반영합니다. 항상 샘플 상황에 대해 확인하세요.
Possible materials
| 재료 | 지원 피크 | Overlapping groups | 인용 출처 |
|---|---|---|---|
| TiO2 | 601, 1700, 1093 | Metal oxygen, Alkyl C-H | 1 |
| PVA | 601, 1660, 2930 | Alkyl C-H | 1 |
| hematite | 601, 1030, 469 | Phosphate (PO4), Metal oxygen | 1 |
| kaolinite | 601, 3696, 693 | Metal oxygen, Phosphate (PO4) | 1 |
| apatite | 601, 3053, 1640 | Phosphate (PO4), Phosphorus, Alkyl C-H | 1 |
| ZnO | 601, 1400, 3430 | Metal oxygen, Alkyl C-H | 1 |
Materials are shown only when the same literature pool supports this band and at least one additional characteristic peak.
Spectrum logic
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 601 cm⁻¹ is usually not enough for material identification by itself.
Real-world usage
This type of query is common in polymer identification, unknown plastic screening, QC troubleshooting, recycled-material verification, and literature-backed peak assignment review.
Common mistakes
- Treating one isolated band as proof of a material without checking at least one or two supporting peaks.
- Ignoring overlap: multiple functional groups can contribute near the same wavenumber.
- Skipping validation when additives, blends, oxidation, or contamination may distort the spectrum.
Verification advice
When ambiguity remains, validate the hypothesis with DSC, GC-MS, or TGA, especially for blends, degraded samples, and filled polymers.
이 할당의 배경이 되는 문헌
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Metal oxygen 신뢰도 1.0
“In addition, v O-P-O bending bands of HA 4 cm-1 cm-1 (601 [8]) and β-TCP (594 [8]) also tends to decrease with manganese addition of 2 mol% 4+ up to 15 mol%.”
Natasha 等 - 2008 - Fourier transform infrared study on sol-gel derive DOI: 10.4028/www.scientific.net/AMR.47-50.1185 -
Metal oxygen 신뢰도 1.0
“Other bands around 847 1 601cm-1 cm-1 and belong to the asymmetric stretching of Ti-O-Ti groups.”
Sathish 等 - 2013 - Nano Composite PVA-TiO2 Thin Films for OTFTs DOI: 10.4028/www.scientific.net/AMR.678.335 -
신뢰도 1.0
“cm-1, spectra of green-synthesized ZnO NPs revealed absorption bands at 601 and 496 FTIR spectra of green-synthesized ZnO NPs revealed absorption bands at 601 and 496 which is a characteristic of the Zn-O connection, which was identified, i”
Green Fabrication of Zinc Oxide Nanoparticles Using Phlomis Leaf Extract: Characterization and In Vitro Evaluation of Cytotoxicity and Antibacterial Properties DOI: 10.3390/molecules26206140 -
Phosphate (PO4) 신뢰도 1.0
“The characteristic bands for PO appear at 601 1050 and 1089 The 43cm-1as bands at 1050 a distinguishable peak, together with observation of the asymmetric P-O stretching of the PO”
Asmi 等 - 2016 - Synthesis and Characterisation of Composite based DOI: 10.1063/1.4945463 -
Phosphate (PO4) 신뢰도 1.0
“The doublet at 601 and 570 cm-1 is due to phosphate bending cm-1, cm-1, at 1090 and 1040 as well as the shoulder at 960 are due to asymmetric and symmetric modes and the sharp peaks at 3573 and 632 cm-1 are assigned to stretching and waggin”
Zirconia/Hydroxyapatite Composites Synthesized Via Sol-Gel: Influence of Hydroxyapatite Content and Heating on Their Biological Properties DOI: 10.3390/ma10070757 -
Alkyl C-H 신뢰도 1.0
“bending vibration bands were recognized at 601 and 477cm-1 The stretching mode energy responds to variations in unit [35], the bending of C-H was observed at 875 cm-1 cell volume via two mechanisms: shifts in bond length and [36].”
Ismail 等 - 2023 - The role of nanoparticles inclusion in monitoring DOI: 10.1007/s41779-023-00836-4 -
Phosphate (PO4) 신뢰도 1.0
“4 1 bending mode of O-P-O bond), 601 cm-1 (ν4 bending mode of O-P-O bond), 957 cm-1 (ν1 symmetric cm-1 (ν mode of P-O bond), and 1033 asymmetric stretching mode of P-O).”
Ma 等 - 2019 - Investigation of the Optical, Physical, and Chemic DOI: 10.3390/su11143803 -
Phosphate (PO4) 신뢰도 0.9
“v2v4(PO4) band”
Novel contribution on the diagenetic physicochemical features of bone and teeth minerals, as substrates for ancient DNA typing DOI: 10.1007/s00216-014-7863-z
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