What absorbs at 601 cm⁻¹ in an FTIR spectrum?
Una banda cerca de 601 cm⁻¹ puede apuntar a varios grupos funcionales. A continuación se muestran las asignaciones más probables, clasificadas por cuánta evidencia publicada respalda cada una — cada una trazable a literatura (DOI) y validada de forma cruzada con nuestros más de 130,000 espectros de referencia y grafo de conocimiento.
Backed by 8 cited sources
Quick answer
A band near 601 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
Posibles asignaciones de grupos funcionales
| Grupo funcional | Hechos de respaldo | Fuentes citadas | Confianza máxima |
|---|---|---|---|
| Phosphate (PO4) | 6 | 6 | 1,0 |
| Metal oxygen | 3 | 3 | 1,0 |
| Phosphorus | 2 | 2 | 1,0 |
| Alkyl C-H | 1 | 1 | 1,0 |
| Carbonate | 1 | 1 | 0,7 |
La clasificación refleja la evidencia acumulada de la literatura, no una única regla autorizada. Siempre confirme según el contexto de su muestra.
Possible materials
| Material | Supporting peaks | Overlapping groups | Fuentes citadas |
|---|---|---|---|
| TiO2 | 601, 1700, 1093 | Metal oxygen, Alkyl C-H | 1 |
| PVA | 601, 1660, 2930 | Alkyl C-H | 1 |
| hematite | 601, 1030, 469 | Phosphate (PO4), Metal oxygen | 1 |
| kaolinite | 601, 3696, 693 | Metal oxygen, Phosphate (PO4) | 1 |
| apatite | 601, 3053, 1640 | Phosphate (PO4), Phosphorus, Alkyl C-H | 1 |
| ZnO | 601, 1400, 3430 | Metal oxygen, Alkyl C-H | 1 |
Materials are shown only when the same literature pool supports this band and at least one additional characteristic peak.
Spectrum logic
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 601 cm⁻¹ is usually not enough for material identification by itself.
Real-world usage
This type of query is common in polymer identification, unknown plastic screening, QC troubleshooting, recycled-material verification, and literature-backed peak assignment review.
Common mistakes
- Treating one isolated band as proof of a material without checking at least one or two supporting peaks.
- Ignoring overlap: multiple functional groups can contribute near the same wavenumber.
- Skipping validation when additives, blends, oxidation, or contamination may distort the spectrum.
Verification advice
When ambiguity remains, validate the hypothesis with DSC, GC-MS, or TGA, especially for blends, degraded samples, and filled polymers.
Literatura detrás de estas asignaciones
-
Metal oxygen confianza 1,0
“In addition, v O-P-O bending bands of HA 4 cm-1 cm-1 (601 [8]) and β-TCP (594 [8]) also tends to decrease with manganese addition of 2 mol% 4+ up to 15 mol%.”
Natasha 等 - 2008 - Fourier transform infrared study on sol-gel derive DOI: 10.4028/www.scientific.net/AMR.47-50.1185 -
Metal oxygen confianza 1,0
“Other bands around 847 1 601cm-1 cm-1 and belong to the asymmetric stretching of Ti-O-Ti groups.”
Sathish 等 - 2013 - Nano Composite PVA-TiO2 Thin Films for OTFTs DOI: 10.4028/www.scientific.net/AMR.678.335 -
confianza 1,0
“cm-1, spectra of green-synthesized ZnO NPs revealed absorption bands at 601 and 496 FTIR spectra of green-synthesized ZnO NPs revealed absorption bands at 601 and 496 which is a characteristic of the Zn-O connection, which was identified, i”
Green Fabrication of Zinc Oxide Nanoparticles Using Phlomis Leaf Extract: Characterization and In Vitro Evaluation of Cytotoxicity and Antibacterial Properties DOI: 10.3390/molecules26206140 -
Phosphate (PO4) confianza 1,0
“The characteristic bands for PO appear at 601 1050 and 1089 The 43cm-1as bands at 1050 a distinguishable peak, together with observation of the asymmetric P-O stretching of the PO”
Asmi 等 - 2016 - Synthesis and Characterisation of Composite based DOI: 10.1063/1.4945463 -
Phosphate (PO4) confianza 1,0
“The doublet at 601 and 570 cm-1 is due to phosphate bending cm-1, cm-1, at 1090 and 1040 as well as the shoulder at 960 are due to asymmetric and symmetric modes and the sharp peaks at 3573 and 632 cm-1 are assigned to stretching and waggin”
Zirconia/Hydroxyapatite Composites Synthesized Via Sol-Gel: Influence of Hydroxyapatite Content and Heating on Their Biological Properties DOI: 10.3390/ma10070757 -
Alkyl C-H confianza 1,0
“bending vibration bands were recognized at 601 and 477cm-1 The stretching mode energy responds to variations in unit [35], the bending of C-H was observed at 875 cm-1 cell volume via two mechanisms: shifts in bond length and [36].”
Ismail 等 - 2023 - The role of nanoparticles inclusion in monitoring DOI: 10.1007/s41779-023-00836-4 -
Phosphate (PO4) confianza 1,0
“4 1 bending mode of O-P-O bond), 601 cm-1 (ν4 bending mode of O-P-O bond), 957 cm-1 (ν1 symmetric cm-1 (ν mode of P-O bond), and 1033 asymmetric stretching mode of P-O).”
Ma 等 - 2019 - Investigation of the Optical, Physical, and Chemic DOI: 10.3390/su11143803 -
Phosphate (PO4) confianza 0,9
“v2v4(PO4) band”
Novel contribution on the diagenetic physicochemical features of bone and teeth minerals, as substrates for ancient DNA typing DOI: 10.1007/s00216-014-7863-z
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