What absorbs at 582 cm⁻¹ in an FTIR spectrum?
A band near 582 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 8 cited sources
Ātra atbilde
A band near 582 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
Iespējamie funkcionālo grupu piešķīrumi
| Funkcionālā grupa | Atbalstošie fakti | Citētie avoti | Augstākā pārliecība |
|---|---|---|---|
| Metal oxygen | 3 | 3 | 1,0 |
| S eq o | 1 | 1 | 1,0 |
| Phosphate (PO4) | 1 | 1 | 1,0 |
| Amide | 1 | 1 | 1,0 |
| C-O single bond | 1 | 1 | 0,9 |
Rangs atspoguļo uzkrātos literatūras pierādījumus, nevis vienu autoritatīvu noteikumu. Vienmēr apstipriniet atbilstoši parauga kontekstam.
Iespējamie materiāli
| Materiāls | Atbalstošie pīķi | Pārklājošās grupas | Citētie avoti |
|---|---|---|---|
| chitosan | 582, 1650, 1655 | Amide | 1 |
| Cellulose | 582, 1735, 1650 | Amide | 1 |
| ZnO | 582, 1400, 3430 | Metal oxygen, Amide | 1 |
| Fe3O4 | 582, 2358, 1673 | Metal oxygen, Amide | 1 |
| iron oxide | 582, 1130, 891 | Metal oxygen | 1 |
| Fe3O4 nanoparticles | 582, 1673, 1470 | Metal oxygen, Amide | 1 |
Materiāli tiek parādīti tikai tad, ja šo joslu un vismaz vienu papildu raksturīgo pīķi atbalsta tā pati literatūras kopa.
Spektra loģika
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 582 cm⁻¹ is usually not enough for material identification by itself.
Reālās pasaules izmantošana
Šāda veida vaicājums ir izplatīts polimēru identificēšanā, nezināmas plastmasas skrīningā, kvalitātes kontroles problēmu risināšanā, pārstrādāto materiālu pārbaudē un ar literatūru pamatotā pīķu piešķīruma pārskatā.
Biežākās kļūdas
- Vienas izolētas joslas uzskatīšana par materiāla pierādījumu, nepārbaudot vismaz vienu vai divus atbalsta pīķus.
- Ignorējot pārklāšanos: vairākas funkcionālās grupas var dot ieguldījumu tuvu tam pašam viļņa skaitlim.
- Izlaist validāciju, ja piedevas, maisījumi, oksidācija vai piesārņojums var izkropļot spektru.
Verifikācijas padoms
Ja joprojām pastāv neskaidrība, apstipriniet hipotēzi ar DSC, GC-MS vai TGA, īpaši maisījumiem, noārdītiem paraugiem un pildītiem polimēriem.
Literatūra aiz šiem piešķīrumiem
-
pārliecība 1,0
“The peak at 582.2 cm is attributed to the Fe-O bond 4”
ENHANCEMENT OF THERMAL IMAGING BY IRON OXIDE NANOPARTICLE – PRELIMINARY STUDY DOI: 10.1016/j.bcab.2018.12.005 -
Amide pārliecība 1,0
“The FTIR peaks at 1,678 and 1,582 cm-1 were attributed to amide I and amide II of pNIPAm which was also present in CS spectra.”
Qureshi 等 - 2015 - Ethyl acetate Salix alba leaves extract-loaded chi DOI: 10.1080/09205063.2015.1100843 -
pārliecība 1,0
“The energy band gap of the NPs was observed toexistintherangeof2.95to3.39eVuponvaryingtheconcentrationofSr2+dopant.Thebroadpeaksat437cm-1and582cm-1 correspond to octahedral (B-) metal stretching (Ni-O) and tetrahedral (A-) metal stretching”
Effect of Sr2+ Ion–Substituted Nickel Ferrite Nanoparticles Prepared by a Simple Microwave Combustion Method DOI: 10.1007/s10948-020-05777-8 -
Phosphate (PO4) pārliecība 1,0
“Vibrations at 582 593 and 606 are attributed to PO cm-1, the υ4 (PO43-) at 570 and 602 cm-1, υ1 (PO43-) at 962 cm-1, and υ3 (PO43-) at 1051 and 4 vibrations (asymmetric O-P-O bending mode) [46,49-51].”
Gavinho 等 - 2023 - An Eco-Friendly Process to Extract Hydroxyapatite DOI: 10.3390/jfb14050279 -
S eq o pārliecība 1,0
“capacity Moreover, there is an enlarged band with a slight change at 582 cm-1 in the composite 55 removal beads, indicating the sulfonic acid group, due to the combination of the bands at 633 and”
Potential Application of Innovative Aspergillus terreus/ Sodium Alginate Composite Beads as Eco-Friendly and Sustainable Adsorbents for Alizarin Red S Dye: Isotherms and Kinetics Models DOI: 10.3390/microorganisms11051135 -
pārliecība 1,0
“cm-1 The bands at 582 may be ascribed to the Zn-O bond [20].”
Toteva 等 - 2021 - Pollutants Sorbent Made of Cotton Fabric Modified DOI: 10.3390/ma14123242 -
C-O single bond pārliecība 0,9
“explicit assignment”
Barzic 等 - 2022 - Cellulose derivativebarium titanate composites wi DOI: 10.21203/rs.3.rs-467926/v1 -
pārliecība 0,7
“Pairwise indexed to stretching vibrations.”
Nguyen 等 - 2019 - A Facile Synthesis, Characterization, and Photocat DOI: 10.1155/2019/3428681
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