What absorbs at 571 cm⁻¹ in an FTIR spectrum?
A band near 571 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 8 cited sources
Réponse rapide
A band near 571 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
Attributions possibles de groupes fonctionnels
| Groupe fonctionnel | Faits à l'appui | Sources citées | Confiance maximale |
|---|---|---|---|
| Phosphorus | 2 | 2 | 1,0 |
| Phosphate (PO4) | 2 | 2 | 1,0 |
| Alkyl C-H | 2 | 2 | 1,0 |
| Methyl | 1 | 1 | 1,0 |
| Hydroxyl (O-H) | 1 | 1 | 1,0 |
| Silanol (Si-OH) | 1 | 1 | 1,0 |
| Aromatic ring | 1 | 1 | 1,0 |
| Ring structure | 1 | 0 | 1,0 |
Le classement reflète les preuves bibliographiques accumulées, et non une règle faisant autorité. Confirmez toujours dans le contexte de votre échantillon.
Matériaux possibles
| Matériel | Pics de support | Groupes chevauchants | Sources citées |
|---|---|---|---|
| apatite | 571, 3053, 1640 | Phosphate (PO4), Phosphorus, Alkyl C-H | 1 |
| hydroxyapatite | 571, 1620, 1639 | Phosphate (PO4), Alkyl C-H, Phosphorus | 1 |
| chitosan | 571, 1650, 1655 | Alkyl C-H | 1 |
| Fe3O4 | 571, 2358, 1673 | Alkyl C-H | 1 |
Les matériaux sont affichés uniquement lorsque le même ensemble de littérature soutient cette bande et au moins un pic caractéristique supplémentaire.
Logique du spectre
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 571 cm⁻¹ is usually not enough for material identification by itself.
Utilisation réelle
Ce type de requête est courant dans l'identification des polymères, le criblage des plastiques inconnus, le dépannage du contrôle qualité, la vérification des matériaux recyclés et l'examen de l'attribution des pics appuyée par la littérature.
Erreurs courantes
- Traiter une bande isolée comme preuve d'un matériau sans vérifier au moins un ou deux pics de support.
- Ignorer le chevauchement : plusieurs groupes fonctionnels peuvent contribuer près du même nombre d'onde.
- Sauter la validation lorsque des additifs, des mélanges, l'oxydation ou la contamination peuvent déformer le spectre.
Conseil de vérification
Lorsque l'ambiguïté persiste, validez l'hypothèse avec DSC, GC-MS ou TGA, en particulier pour les mélanges, les échantillons dégradés et les polymères chargés.
Bibliographie derrière ces attributions
-
Aromatic ring confiance 1,0
“in SSSAJ: Volume 75: Number 2 • March-April 2011 571 cm-1 1238 could be due to aromatic-CH in plane deformation Particulate OM makes up 5 to 23% of the SOC, with the and has high partial least squares regression loadings for TOC smaller pro”
Calderon 等 - 2011 - Chemical Differences in Soil Organic Matter Fracti DOI: 10.2136/sssaj2009.0375 -
Silanol (Si-OH) confiance 1,0
“Series: Materials Science and Engineering (2017) 012047 doi:10.1088/1757-899X/202/1/012047 cm-1 cm-1 Si-Fe-O at 570.93 [6, 17], Si-OH stretching at 779.24 [11], and Si-O-Si stretching cm-1 asymmetric at 1049.28 [6, 15] clearly show the pres”
Deswardani 等 - 2017 - Study of Structural and Magnetic Properties of Sil DOI: 10.1088/1757-899X/202/1/012047 -
confiance 1,0
“Further, FT-IR spectroscopy reveals for Fe 3O a band at 571 which shows 4 4 theFe-Ostretchingmodeoftetrahedralandoctahedralsites.Formationofγ-Fe 2O 3uponannealingwasagainconfirmedfromthe cm-1 cm-1 cm-1.”
Yadav 等 - 2020 - Facile Synthesis of Substantially Magnetic Hollow DOI: 10.1007/s10948-020-05481-7 -
Alkyl C-H confiance 1,0
“LLM confirmed rule peak-group candidate”
Development of New Amphiphilic Catalytic Steam Additives for Hydrothermal Enhanced Oil Recovery Techniques DOI: 10.3390/catal12080921 -
Phosphate (PO4) confiance 1,0
“One strong and relatively broad band at 1062.78cm-1, two relatively strong and sharp bands at 570.95cm-1 603.71cm-1, and and another band at ABC 956.69cm-1 have appeared due to the presence of the 43-) phosphate (PO group of HAp.”
Malla 等 - 2020 - Extraction and Characterization of Novel Natural H DOI: 10.1155/2020/1690178 -
Phosphate (PO4) confiance 1,0
“The peaks cm-1 at 571, 604, 983, 1035, and 1098 are associated with the vibrational modes of the phosphate groups.”
Composition and content analysis of fluoride in inorganic salts of the integument of Antarctic krill (Euphausia superba) DOI: 10.1038/s41598-019-44337-6 -
confiance 0,9
“Explicit assignment in text.”
Spectral characterization of hydroxyapatite extracted from Black Sumatra and Fighting cock bone samples: A comparative analysis DOI: 10.1016/j.sjbs.2020.11.020 -
confiance 0,8
“Text: 'KBR absorption peak used as pellets'.”
Zam 等 - 2021 - Identification of chitosan beads from coconut crab DOI: 10.1088/1742-6596/1832/1/012014
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