What absorbs at 479 cm⁻¹ in an FTIR spectrum?
A band near 479 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 8 cited sources
クイックアンサー
A band near 479 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
可能性のある官能基アサイン
| 官能基 | 裏付け事実 | 引用元 | 最高信頼度 |
|---|---|---|---|
| Metal oxygen | 3 | 3 | 1.0 |
| Silicon-oxygen (Si-O) | 1 | 1 | 1.0 |
| Phosphate (PO4) | 1 | 1 | 1.0 |
| Alkyl C-H | 1 | 1 | 1.0 |
| Carbon dioxide | 1 | 1 | 1.0 |
| N h | 1 | 1 | 1.0 |
ランキングは蓄積された文献証拠を反映しており、単一の権威あるルールではありません。常にサンプルのコンテキストと照合して確認してください。
可能性のある材料
| 素材 | 補助ピーク | 重複グループ | 引用元 |
|---|---|---|---|
| Silica | 479, 1100, 1080 | Silicon-oxygen (Si-O), Alkyl C-H | 1 |
| AgNPs | 479, 1232, 1048 | Alkyl C-H | 1 |
| polystyrene | 479, 1020, 1600 | Alkyl C-H | 1 |
同じ文献プールがこのバンドと少なくとも1つの追加の特性ピークをサポートする場合にのみ、材料が表示されます。
スペクトルロジック
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 479 cm⁻¹ is usually not enough for material identification by itself.
実使用例
この種のクエリは、ポリマー識別、未知のプラスチックスクリーニング、QCトラブルシューティング、リサイクル材料の検証、および文献に基づいたピーク帰属のレビューで一般的です。
よくある間違い
- 少なくとも1~2つの支持ピークを確認せずに、1つの孤立したバンドを材料の証拠として扱うこと。
- 重複を無視: 複数の官能基が同じ波数付近に寄与することがあります。
- 添加剤、ブレンド、酸化、または汚染がスペクトルを歪める可能性がある場合に検証を省略すること。
検証アドバイス
曖昧さが残る場合は、特にブレンド、劣化サンプル、充填ポリマーについて、DSC、GC-MS、またはTGAで仮説を検証してください。
これらのアサインの根拠となる文献
-
信頼度 1.0
“Evaluation of leaf aqueous extract and synthesized silver & Mathath Roni Kadarkarai Murugan & Chellasamy Panneerselvam Jayapal Subramaniam Received: 2 November 2012/Accepted: 22 November 2012/Published online: 13 December 2012 # Springer-Ve”
Roni 等 - 2013 - Evaluation of leaf aqueous extract and synthesized DOI: 10.1007/s00436-012-3220-3 -
Carbon dioxide 信頼度 1.0
“cm-1, cm-1, cm-1 lowest frequency band, observed at 478.71 474.91 472.12 is assigned to the Fe3+↔O, Co2+↔O octahedral metal stretching of given in Table 2.”
Synthesis, Structural, Optical, Electrical and Mössbauer spectroscopic studies of Co substituted Li0.5Fe2.5O4 DOI: 10.1016/j.jmmm.2016.01.023 -
信頼度 1.0
“RHE, two peaks appeared at 479 the corresponding current on the CV curve increased rapidly, which revealed that Ni oxyhydroxides formed on the reconstructed surface of Ni2P/NF were the real active sites for catalyzing the ammonia decomposit”
Ni(II)/Ni(III) redox couple endows Ni foam-supported Ni2P with excellent capability for direct ammonia oxidation DOI: 10.1016/j.cej.2020.126795 -
Alkyl C-H 信頼度 1.0
“CO (stretching) + CCH (stretching) + ring of pyranose (antisymmetric stretching) stretching)/C-O 1255 CO (stretching) + CCH (stretching) + ring of pyranose (antisymmetric (stretching), alcohol, ester, ether, carboxylic acid C-N+ 1078 (symme”
Hayyan 等 - 2015 - Functionalization of graphene using deep eutectic DOI: 10.1186/s11671-015-1004-2 -
信頼度 1.0
“The I 6 cm-1 peak at 479 represents the bending normal vibrations of the Ti-O bond.”
Fabrication of Europium-Doped Barium Titanate/Polystyrene Polymer Nanocomposites Using Ultrasonication-Assisted Method: Structural and Optical Properties DOI: 10.3390/polym14214664 -
Phosphate (PO4) 信頼度 1.0
“Based on the listed deconvolution parameters in Table 2, the band at 479 cm-1 is attributed to the bending vibrations of O-P-O in (PO2-)n chain groups [18].”
The Influence of CoO/P2O5 Substitutions on the Structural, Mechanical, and Radiation Shielding of Boro-Phosphate Glasses DOI: 10.3390/ma14216632 -
信頼度 1.0
“cm-1 for Si-O-Si groups (stretching and bending vibrations, respectively), 968 cm-1 for Si-OH groups cm-1 cm-1 813 for Si-O-Si groups (stretching and bending vibrations, respectively), 968 for Si-OH (stretching vibrations) and 479 cm-1 for”
Zdarta 等 - 2017 - Lipase B from Candida antarctica Immobilized on a DOI: 10.3390/catal7010014 -
信頼度 0.9
“Peak at 479 cm-1 assigned to free SiO4.”
Phase Composition of Silica Fume—Portland Cement Systems Formed under Hydrothermal Curing Evaluated by FTIR, XRD, and TGA DOI: 10.3390/ma14112786
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