What absorbs at 407 cm⁻¹ in an FTIR spectrum?
A band near 407 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 4 cited sources
Quick answer
A band near 407 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
Mogelijke functionele-groeptoewijzingen
| Functionele groep | Ondersteunende feiten | Geciteerde bronnen | Hoogste vertrouwen |
|---|---|---|---|
| Metal oxygen | 1 | 1 | 1,0 |
| N-O bond | 1 | 1 | 1,0 |
| C c single bond | 1 | 1 | 1,0 |
| C-O single bond | 1 | 1 | 1,0 |
| Nitrate | 1 | 0 | 1,0 |
Ranglijst weerspiegelt cumulatief literatuurbewijs, niet één gezaghebbende regel. Bevestig altijd aan de hand van uw monsterecontext.
Possible materials
| Materiaal | Ondersteunende pieken | Overlapping groups | Geciteerde bronnen |
|---|---|---|---|
| ZnO | 407, 1400, 3430 | Metal oxygen, C-O single bond | 1 |
Materials are shown only when the same literature pool supports this band and at least one additional characteristic peak.
Spectrum logic
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 407 cm⁻¹ is usually not enough for material identification by itself.
Real-world usage
This type of query is common in polymer identification, unknown plastic screening, QC troubleshooting, recycled-material verification, and literature-backed peak assignment review.
Common mistakes
- Treating one isolated band as proof of a material without checking at least one or two supporting peaks.
- Ignoring overlap: multiple functional groups can contribute near the same wavenumber.
- Skipping validation when additives, blends, oxidation, or contamination may distort the spectrum.
Verification advice
When ambiguity remains, validate the hypothesis with DSC, GC-MS, or TGA, especially for blends, degraded samples, and filled polymers.
Literatuur achter deze toewijzingen
-
vertrouwen 1,0
“Utilising this calibration curve, from the 3reaction mixture IR spectrums, the product mixture composition detect any meaningful nitrogen peaks for NO around 407 eV (or even”
A new approach to silver-catalysed aerobic oxidation of octadecanol: Probing catalysts utilising a flat, two-dimensional silicon-based model support system DOI: 10.1016/j.catcom.2012.07.013 -
C-O single bond vertrouwen 1,0
“Furthermore, the O-C-C scissoring (407 cm-1) of CS 2, EtOH, CO, CO 2, COS, H 2O, SO 2, EtSH, Et 2S, 436 of the ethyl group has disappeared, in correlation Et 2O, and (EX) in a proportionally smaller quantity, with EGA-MS results, where evol”
Thermal decomposition of tris(O-ethyldithiocarbonato)-antimony(III)—a single-source precursor for antimony sulfide thin films DOI: 10.1007/s10973-021-10885-1 -
N-O bond vertrouwen 1,0
“Thus, TiC and TiO have no band gap at E F 407.”
Fernandes 等 - 2006 - Property change in multifunctional TiCxOy thin fil DOI: 10.1016/j.tsf.2006.07.047 -
vertrouwen 1,0
“cm-1, 407 These bands are assigned to the Zn-O stretching vibrations [10].”
Ivanova 等 - 2020 - Deposition and study of N-In co-doped sol-gel ZnO DOI: 10.1088/1742-6596/1492/1/012027
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