What absorbs at 3618 cm⁻¹ in an FTIR spectrum?
A band near 3618 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 7 cited sources
Hiter odgovor
A band near 3618 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
Možne dodelitve funkcionalnih skupin
| Funkcionalna skupina | Podporna dejstva | Citirani viri | Najvišje zaupanje |
|---|---|---|---|
| Hydroxyl (O-H) | 4 | 4 | 1,0 |
| Alkyl C-H | 2 | 2 | 1,0 |
| Metal hydroxyl | 1 | 1 | 0,8 |
Razvrstitev odraža zbrane literaturne dokaze, ne enega avtoritativnega pravila. Vedno preverite glede na kontekst vašega vzorca.
Možni materiali
| Material | Podporni vrhovi | Prekrivajoče se skupine | Citirani viri |
|---|---|---|---|
| oil shale | 3618, 1625, 1053 | Alkyl C-H, Hydroxyl (O-H) | 1 |
Materiali so prikazani le, ko ista literaturna podlaga podpira ta pas in vsaj en dodatni karakteristični vrh.
Logika spektra
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 3618 cm⁻¹ is usually not enough for material identification by itself.
Uporaba v resničnem svetu
Ta vrsta poizvedbe je pogosta pri identifikaciji polimerov, pregledovanju neznanih plastičnih mas, odpravljanju težav pri QC, preverjanju recikliranih materialov in literaturno podprtem pregledu dodelitev vrhov.
Pogoste napake
- Obravnavanje enega izoliranega pasu kot dokaza o materialu brez preverjanja vsaj enega ali dveh podpornih vrhov.
- Ignoriranje prekrivanja: več funkcionalnih skupin lahko prispeva blizu istega valovnega števila.
- Izpuščanje validacije, ko lahko dodatki, mešanice, oksidacija ali kontaminacija popačijo spekter.
Nasvet za preverjanje
Ko ostaja dvoumnost, potrdite hipotezo z DSC, GC-MS ali TGA, zlasti za mešanice, degradirane vzorce in polnjene polimere.
Literatura za temi dodelitvami
-
Alkyl C-H zaupanje 1,0
“cm-1 C-H in the Peaks at 3618 and 3709 are Kaolinite[12,26].”
Zhao 等 - 2015 - Evaluation of Oil Yield of Oil Shale by Infrared S DOI: 10.1007/s40242-015-4364-3 -
zaupanje 1,0
“[36] 2011 Al-Fe-OH the symmetric stretching bands at 3324 and 3618 cm-1 correspond to and 3445-3440 Zeoliticwater”
Benjamin Ortega-Lazcano 等 - 2021 - Study of Pigments from the Colonial Convent of Act DOI: 10.3390/min11080852 -
zaupanje 1,0
“This latter amphibole indeed represents a reference point 3618 cm-1, whose relative intensities are correlated with the Mg/Fe2+ ratio at M(1,3).”
Della Ventura 等 - 2018 - Infra Red Spectroscopy of the Regulated Asbestos A DOI: 10.3390/min8090413 -
Hydroxyl (O-H) zaupanje 1,0
“LLM confirmed rule peak-group candidate”
Morphology and Selected Properties of Modified Potato Thermoplastic Starch DOI: 10.3390/polym15071762 -
Alkyl C-H zaupanje 1,0
“and 3618 The peak related to the asymmetric stretching vibration of methylene at cm-1 2920 [40] was clearly visible in all techniques, while the peak related to the symmetric cm-1 stretching vibration of aliphatic methylene at 2850 [26] was”
Application of FTIR-PAS in Rapid Assessment of Rice Quality under Climate Change Conditions DOI: 10.3390/foods10010159 -
Hydroxyl (O-H) zaupanje 0,95
“Text: 'peak at ν = 3618 is due to OH stretching frequencies'”
Microsoft Word - Finished - Mineral Identification of Rocks From Pohon Batu Hot Springs in West Seram Using FTIR Spectroscopy DOI: 10.1088/1742-6596/1572/1/012045 -
Hydroxyl (O-H) zaupanje 0,8
“Assigned to stretching vibration of hydroxyl groups.”
Multi-Method Analysis of Painting Materials in Murals of the North Mosque (Linqing, China) DOI: 10.3390/coatings13071298
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