What absorbs at 3319 cm⁻¹ in an FTIR spectrum?
A band near 3319 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 8 cited sources
Brzi odgovor
A band near 3319 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
Moguće dodjele funkcionalnih skupina
| Funkcionalna skupina | Potporni dokazi | Citirani izvori | Najveća pouzdanost |
|---|---|---|---|
| Hydroxyl (O-H) | 6 | 5 | 1,0 |
| N h | 4 | 4 | 1,0 |
| Water (H2O) | 2 | 2 | 1,0 |
| Lignin | 1 | 1 | 1,0 |
| Secondary amine | 1 | 1 | 1,0 |
| Alkyl C-H | 1 | 1 | 1,0 |
Rangiranje odražava akumulirane literaturne dokaze, a ne jedno autoritativno pravilo. Uvijek provjerite u kontekstu vašeg uzorka.
Mogući materijali
| Materijal | Potporni vrhovi | Preklapajuće skupine | Citirani izvori |
|---|---|---|---|
| cellulose | 3319, 1735, 1650 | Hydroxyl (O-H) | 1 |
| nanoparticles | 3319, 1732, 1647 | Hydroxyl (O-H) | 1 |
Materijali su prikazani samo kada ista literatura podržava ovu traku i barem jedan dodatni karakteristični vrh.
Logika spektra
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 3319 cm⁻¹ is usually not enough for material identification by itself.
Upotreba u stvarnom svijetu
Ova vrsta upita uobičajena je u identifikaciji polimera, probiru nepoznate plastike, rješavanju problema u kontroli kvalitete, provjeri recikliranog materijala i pregledu dodjele vrhova potkrijepljenom literaturom.
Uobičajene pogreške
- Tretiranje jedne izolirane vrpce kao dokaza materijala bez provjere barem jednog ili dva podržavajuća pika.
- Zanemarivanje preklapanja: više funkcionalnih skupina može doprinositi u blizini istog valnog broja.
- Preskakanje validacije kada aditivi, mješavine, oksidacija ili kontaminacija mogu izobličiti spektar.
Savjet za provjeru
Kada nejasnoća ostane, validirajte hipotezu pomoću DSC, GC-MS ili TGA, posebno za mješavine, degradirane uzorke i punjene polimere.
Literatura iza ovih dodjela
-
Hydroxyl (O-H) pouzdanost 1,0
“[41-42] IR analysis of the whole plant extract of Gotu kola revealed that the presence of different functional groups ranging from O-H stretching, hydroxyl (3319.26 cm-1), C-H stretching, carbonyl (2921.96 cm-1), C=C”
Kumar 等 - 2021 - Centella asiatica mediated facile green synthesis DOI: 10.1016/j.inoche.2021.108865 -
Hydroxyl (O-H) pouzdanost 1,0
“were observed in the spectral ranges of 2614-4000 and 1465-1853 The FTIR spectra of fresh and cm-1, spoiled beetroot test samples showed wide and strong bands at 3319 and 1637 which corresponded to asymmetric and symmetric stretching vibrat”
Analysis of Moisture Content in Beetroot using Fourier Transform Infrared Spectroscopy and by Principal Component Analysis DOI: 10.1038/s41598-018-26243-5 -
N h pouzdanost 1,0
“The remaining band at 1599 cm-1 sites.20,33 acid The final peak at 3319 results from attributed to the asymmetric deformation of NH ((cid:228) as(NH 3)) 3 sites.20 as(NH 3) coordinated to Lewis acid (cid:238)”
Pena 等 - 2004 - Identification of surface species on titania-suppo DOI: 10.1021/jp0313122 -
Water (H2O) pouzdanost 1,0
“Pure distilled water showed a strong IR absorbance band at 3319.48 cm-1 stretching) and around 1636.63 (H-O-H bending).”
Chemometric analysis of cow dung ash as an adsorbent for purifying biodiesel from waste cooking oil DOI: 10.1038/s41598-017-09881-z -
pouzdanost 1,0
“The medium peak at cm-1 3319 represents N-H stretching vibration that showed Significance of each individual process variables and overall the presence of amine group on the surface of biosorbent.”
Biosorption of copper(II) onto spent biomass of Gelidiella acerosa (brown marine algae): optimization and kinetic studies DOI: 10.1007/s13201-019-1125-3 -
Hydroxyl (O-H) pouzdanost 1,0
“The band at cm-1 3319 is attributed to the OH groups in lignin.”
Chemical functional groups of extractives, cellulose and lignin extracted from native Leucaena leucocephala bark DOI: 10.1007/s00226-020-01258-2 -
pouzdanost 1,0
“1c shows the IR A spectrum of 15DAN monomer, which displayed the characteristic peaks at 3416 and u t h 3319cm-1 and are ascribed to N-H stretching of the primary amino groups [32], these dual o”
Olanipekun 等 - 2015 - Synthesis and characterization of reduced graphite DOI: 10.1016/j.saa. -
pouzdanost 1,0
“trum of the Por-BZ monomer, with the main characteristic signals being those for the heat of 163 J Compared with the typical thermal curing temperature of a Pa-type BZ oxazine ring (948 cm-1), C-O stretching (1222 cm-1), and N-H stretching”
Zhang 等 - 2022 - Metal Complexes of the Porphyrin-Functionalized Po DOI: 10.3390/polym14030449
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