What absorbs at 3072 cm⁻¹ in an FTIR spectrum?
A band near 3072 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 7 cited sources
Brzi odgovor
A band near 3072 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
Moguće dodjele funkcionalnih skupina
| Funkcionalna skupina | Potporni dokazi | Citirani izvori | Najveća pouzdanost |
|---|---|---|---|
| Alkyl C-H | 5 | 5 | 1,0 |
| Aromatic ring | 2 | 2 | 1,0 |
| Amide | 1 | 1 | 1,0 |
| Alkene (C=C) | 1 | 1 | 1,0 |
| Hydroxyl (O-H) | 1 | 1 | 0,7 |
Rangiranje odražava akumulirane literaturne dokaze, a ne jedno autoritativno pravilo. Uvijek provjerite u kontekstu vašeg uzorka.
Mogući materijali
| Materijal | Potporni vrhovi | Preklapajuće skupine | Citirani izvori |
|---|---|---|---|
| silk fibroin | 3072, 1050, 1511 | Amide, Alkyl C-H | 1 |
Materijali su prikazani samo kada ista literatura podržava ovu traku i barem jedan dodatni karakteristični vrh.
Logika spektra
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 3072 cm⁻¹ is usually not enough for material identification by itself.
Upotreba u stvarnom svijetu
Ova vrsta upita uobičajena je u identifikaciji polimera, probiru nepoznate plastike, rješavanju problema u kontroli kvalitete, provjeri recikliranog materijala i pregledu dodjele vrhova potkrijepljenom literaturom.
Uobičajene pogreške
- Tretiranje jedne izolirane vrpce kao dokaza materijala bez provjere barem jednog ili dva podržavajuća pika.
- Zanemarivanje preklapanja: više funkcionalnih skupina može doprinositi u blizini istog valnog broja.
- Preskakanje validacije kada aditivi, mješavine, oksidacija ili kontaminacija mogu izobličiti spektar.
Savjet za provjeru
Kada nejasnoća ostane, validirajte hipotezu pomoću DSC, GC-MS ili TGA, posebno za mješavine, degradirane uzorke i punjene polimere.
Literatura iza ovih dodjela
-
Alkyl C-H pouzdanost 1,0
“The band at 3072 corresponding to originating from the cm-1, as(=CH) of the vinyl groups.”
Ilic-Stojanovic 等 - 2018 - Thermosensitive hydrogels for modified release of DOI: 10.1080/00914037.2017.1354202 -
Alkyl C-H pouzdanost 1,0
“This observation is confirmed by the presence of the cm-1, signals from C-H stretching vibrations located at 3072, 2947, and 2874 observed in figure 2(c), which also correspond to gelatin (M.”
Nieto-Villena 等 - 2018 - Infrared Ellipsometry Analysis of Heritage Photogr DOI: 10.1080/00393630.2018.1476962 -
Alkyl C-H pouzdanost 1,0
“Lastly, to complement at 3072 cm-1 for Poly(Ani-AMPS), ascribed to C-H stretching vibrations of the aromatic”
Role of the Anilinium Ion on the Selective Polymerization of Anilinium 2-Acrylamide-2-methyl-1-propanesulfonate DOI: 10.3390/polym13142349 -
Alkyl C-H pouzdanost 1,0
“40 140 240 340 440 540 640 cm-1), 3500 the stretching vibrations of = C-H and C Ar-H Temperature/°C cm-1), (3072 the stretching vibrations of C-H 012345 cm-1), (2720-2990 the stretching vibrations of C=O”
Thermal studies on the starch-g-copolymers prepared from two terpene acrylate monomers under oxidative conditions DOI: 10.1007/s10973-019-08036-8 -
Aromatic ring pouzdanost 0,9
“Explicit assignment: C-H region at 3072 for aromatic stretching”
Coumarin–carbazole based functionalized pyrazolines: synthesis, characterization, anticancer investigation and molecular docking DOI: 10.1039/d1ra03970a -
Alkyl C-H pouzdanost 0,8
“ν(C-H) stretching.”
A Hybrid {Silk@Zirconium MOF} Material as Highly Efficient AsIII-sponge DOI: 10.1038/s41598-020-66091-w -
Hydroxyl (O-H) pouzdanost 0,7
“OH harmonic stretching frequency”
Growth, structure, Hirshfeld surface and spectroscopic properties of 2-amino-4-hydroxy-6-methylpyrimidinium-2,3-pyrazinedicorboxylate single crystal DOI: 10.1016/j.molstruc.2017.11.019
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