What absorbs at 2989 cm⁻¹ in an FTIR spectrum?
A band near 2989 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 7 cited sources
Hiter odgovor
A band near 2989 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
Možne dodelitve funkcionalnih skupin
| Funkcionalna skupina | Podporna dejstva | Citirani viri | Najvišje zaupanje |
|---|---|---|---|
| Alkyl C-H | 5 | 5 | 1,0 |
| Hydroxyl (O-H) | 2 | 2 | 1,0 |
| Imide | 1 | 1 | 1,0 |
| Secondary amine | 1 | 0 | 1,0 |
| N h | 1 | 0 | 1,0 |
Razvrstitev odraža zbrane literaturne dokaze, ne enega avtoritativnega pravila. Vedno preverite glede na kontekst vašega vzorca.
Možni materiali
| Material | Podporni vrhovi | Prekrivajoče se skupine | Citirani viri |
|---|---|---|---|
| polypropylene | 2989, 1030, 1600 | Alkyl C-H, Hydroxyl (O-H) | 1 |
| PLA | 2989, 1650, 1073 | Alkyl C-H, Hydroxyl (O-H) | 1 |
Materiali so prikazani le, ko ista literaturna podlaga podpira ta pas in vsaj en dodatni karakteristični vrh.
Logika spektra
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 2989 cm⁻¹ is usually not enough for material identification by itself.
Uporaba v resničnem svetu
Ta vrsta poizvedbe je pogosta pri identifikaciji polimerov, pregledovanju neznanih plastičnih mas, odpravljanju težav pri QC, preverjanju recikliranih materialov in literaturno podprtem pregledu dodelitev vrhov.
Pogoste napake
- Obravnavanje enega izoliranega pasu kot dokaza o materialu brez preverjanja vsaj enega ali dveh podpornih vrhov.
- Ignoriranje prekrivanja: več funkcionalnih skupin lahko prispeva blizu istega valovnega števila.
- Izpuščanje validacije, ko lahko dodatki, mešanice, oksidacija ali kontaminacija popačijo spekter.
Nasvet za preverjanje
Ko ostaja dvoumnost, potrdite hipotezo z DSC, GC-MS ali TGA, zlasti za mešanice, degradirane vzorce in polnjene polimere.
Literatura za temi dodelitvami
-
Alkyl C-H zaupanje 1,0
“peak at 2714 New peaks attributable to a dimethylacetal, C-H) HC(OCH 3) 2, appeared at 2832 (acetal carbon and 2989 cm-1 for the methyl groups.”
Razgon 等 - 2008 - Ozonolysis-based route to the in situ formation of DOI: 10.1021/la703120c -
Alkyl C-H zaupanje 1,0
“cm-1 In case of AMPS, peak at 2989 is attributed to C-H stretching of-CH2 group.”
Development, characterization and In-vitro evaluation of guar gum based new polymeric matrices for controlled delivery using metformin HCl as model drug DOI: 10.1371/journal.pone.0271623 -
Hydroxyl (O-H) zaupanje 1,0
“The broad negative associated regions between 3259 Regression coefficients of xylose and glucose prediction cm-1 (r and 2989 correspond to the O-H stretching vibraThe high correlation = 0.82) of the measured glucose tion of various compound”
Rapid estimation of sugar release from winter wheat straw during bioethanol production using FTIR-photoacoustic spectroscopy DOI: 10.1186/s13068-015-0267-2 -
Alkyl C-H zaupanje 1,0
“LLM confirmed rule peak-group candidate”
Silva 等 - 2020 - Theoretical and Experimental Investigations on Inc DOI: 10.21577/0103-5053.20190273 -
Imide zaupanje 1,0
“The bismaleThe absorptions around 2989 and 2912 due to the m-cresol imide (1 g, 0.002321 mol) was dissolved in (3.5 mL) C-H stretching vibration of CH group as shown in Fig.”
Sivasankari 等 - 2013 - Synthesis and Characterization of Thiophene Contai DOI: 10.14233/ajchem.2013.13514 -
Alkyl C-H zaupanje 0,9
“Explicit assignment from text.”
Partial Biodegradable Blend with High Stability against Biodegradation for Fused Deposition Modeling DOI: 10.3390/polym14081541 -
Hydroxyl (O-H) zaupanje 0,9
“C-H vibration of OH group”
Poly lactic acid production using the ring opening polymerization (ROP) method using Lewis acid surfactant combined iron (Fe) catalyst (Fe(DS)3) DOI: 10.1016/j.heliyon.2023.e17985
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