What absorbs at 2977 cm⁻¹ in an FTIR spectrum?
A band near 2977 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 8 cited sources
快速回答
A band near 2977 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
可能的官能基指派
| 官能基 | 支持事實 | 引用來源 | 最高信心 |
|---|---|---|---|
| Alkyl C-H | 10 | 10 | 1.0 |
| Ring structure | 1 | 1 | 1.0 |
| Carbohydrate | 1 | 1 | 1.0 |
排名反映累積的文獻證據,而非單一權威規則。請務必根據您的樣品背景進行確認。
可能的材料
| 材料 | 支持峰 | 重疊基團 | 引用來源 |
|---|---|---|---|
| cellulose | 2977, 1735, 1650 | Alkyl C-H, Carbohydrate | 1 |
| hemicellulose | 2977, 1730, 897 | Alkyl C-H | 1 |
| lignin | 2977, 1035, 1510 | Alkyl C-H | 1 |
| biomass | 2977, 1082, 1282 | Alkyl C-H | 1 |
僅當同一文獻庫支援此波段以及至少一個額外特徵峰時,才會顯示材料。
光譜邏輯
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 2977 cm⁻¹ is usually not enough for material identification by itself.
實際使用
此類查詢常見於聚合物鑑別、未知塑膠篩選、品管故障排除、再生材料驗證,以及基於文獻的峰值歸屬審查。
常見錯誤
- 將一個孤立的譜帶視為材料的證據,而未檢查至少一兩個支持峰。
- 忽略重疊:多個官能團可能在相同波數附近貢獻。
- 當添加劑、混合物、氧化或污染物可能扭曲譜圖時,跳過驗證。
驗證建議
當仍然存在歧義時,使用DSC、GC-MS或TGA驗證假設,特別是對於混合物、降解樣品和填充聚合物。
這些指派背後的文獻
-
Alkyl C-H 信心 1.0
“cm-1 The peaks that appear at 2977 and 2898 were 3.3 FTIR-ATR spectroscopy characterization associated with the stretching of the C-H bond.”
Mondragon-Cortez 等 - 2022 - Application of Fourier transform infrared spectros DOI: 10.24275/rmiq/Alim2806 -
Alkyl C-H 信心 1.0
“These waveband peak results 2977 is attributed to the C-H vibrations of the may indicate a reduction in sugar, which would and -CH moiety vibrations in alkyl group and -CH 2”
Use of thermal imaging and Fourier transform infrared spectroscopy for the pre-symptomatic detection of cucumber downy mildew DOI: 10.1007/s10658-019-01775-2 -
Alkyl C-H 信心 1.0
“LLM confirmed rule peak-group candidate”
Ajibade 和 Mbese - 2014 - Synthesis and Characterization of Metal Sulfides N DOI: 10.1155/2014/752394 -
Alkyl C-H 信心 1.0
“Bond (vibration) Degradation product 2977 C-H (asymmetric stretching) C xH y”
Hejna 等 - 2017 - Performance properties of rigid polyurethane-polyi DOI: 10.1515/epoly-2017-0012 -
Alkyl C-H 信心 1.0
“at 2977 and 2924 cm-1 due to stretching vibration of C-H (the bands at 2994, 2977, 2924, 2904 and 2890 would be due to”
Oliveira 等 - 2016 - FTIR analysis and quantification of phenols and fl DOI: 10.1590/S1517-707620160003.0072 -
Alkyl C-H 信心 1.0
“peaks at 2977 and 2931 were cm-1 assigned to C-H stretching vibration within the ring;”
In Vitro Interaction of Doxorubicin-Loaded Silk Sericin Nanocarriers with MCF-7 Breast Cancer Cells Leads to DNA Damage DOI: 10.3390/polym13132047 -
Alkyl C-H 信心 1.0
“The absorptions at 2977 and 2929, cm-1 2900 are allocated to symmetric and anti-symmetric vibration of CH in the alkyl chain in EO, tween 20, 2”
Nanoliposomes containing three essential oils from the Artemisia genus as effective larvicides against Aedes aegypti and Anopheles stephensi DOI: 10.1038/s41598-023-38284-6 -
Alkyl C-H 信心 1.0
“1026 C-O stretching 2977 C-H stretching 2875 C-H stretching”
Zhuang 等 - 2020 - Observation of Potential Contaminants in Processed DOI: 10.3390/app10124345
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