What absorbs at 2887 cm⁻¹ in an FTIR spectrum?
A band near 2887 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 6 cited sources
Hiter odgovor
A band near 2887 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
Možne dodelitve funkcionalnih skupin
| Funkcionalna skupina | Podporna dejstva | Citirani viri | Najvišje zaupanje |
|---|---|---|---|
| Alkyl C-H | 5 | 4 | 1,0 |
| Methyl | 2 | 2 | 1,0 |
| Hydroxyl (O-H) | 2 | 1 | 1,0 |
| Phosphate (PO4) | 1 | 1 | 1,0 |
| Water (H2O) | 1 | 1 | 1,0 |
| Carbohydrate | 1 | 1 | 1,0 |
Razvrstitev odraža zbrane literaturne dokaze, ne enega avtoritativnega pravila. Vedno preverite glede na kontekst vašega vzorca.
Možni materiali
| Material | Podporni vrhovi | Prekrivajoče se skupine | Citirani viri |
|---|---|---|---|
| Starch | 2887, 1650, 1540 | Hydroxyl (O-H), Alkyl C-H | 2 |
| glycerol | 2887, 1585, 1630 | Alkyl C-H, Hydroxyl (O-H) | 1 |
Materiali so prikazani le, ko ista literaturna podlaga podpira ta pas in vsaj en dodatni karakteristični vrh.
Logika spektra
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 2887 cm⁻¹ is usually not enough for material identification by itself.
Uporaba v resničnem svetu
Ta vrsta poizvedbe je pogosta pri identifikaciji polimerov, pregledovanju neznanih plastičnih mas, odpravljanju težav pri QC, preverjanju recikliranih materialov in literaturno podprtem pregledu dodelitev vrhov.
Pogoste napake
- Obravnavanje enega izoliranega pasu kot dokaza o materialu brez preverjanja vsaj enega ali dveh podpornih vrhov.
- Ignoriranje prekrivanja: več funkcionalnih skupin lahko prispeva blizu istega valovnega števila.
- Izpuščanje validacije, ko lahko dodatki, mešanice, oksidacija ali kontaminacija popačijo spekter.
Nasvet za preverjanje
Ko ostaja dvoumnost, potrdite hipotezo z DSC, GC-MS ali TGA, zlasti za mešanice, degradirane vzorce in polnjene polimere.
Literatura za temi dodelitvami
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Alkyl C-H zaupanje 1,0
“cm´1, for the OH group of pure PHB appears between 3200 and 4000 but the broad band of the OH The stretching peaks at 1452, 1379, 1223, and 2887 cm-1 correspond to the methyl group.”
Influence of Electrospinning Parameters on Fiber Diameter and Mechanical Properties of Poly(3-Hydroxybutyrate) (PHB) and Polyanilines (PANI) Blends DOI: 10.3390/polym8030097 -
Carbohydrate zaupanje 1,0
“4000 3500 3000 2500 2000 1500 1000 stronger hydrogen bonding could be concluded from the double (cm-1) Wave Number 2919cm-1 2887cm-1 999cm-1 992cm-1 peaks at to and to in nanocomposites samples when compared with pure starch (Ding, Ainswort”
Glycerol/starch/Na+-montmorillonite nanocomposites: A XRD, FTIR, DSC and 1H NMR study DOI: 10.1016/j.carbpol.2010.10.018 -
Alkyl C-H zaupanje 1,0
“Instead, the large cm-1 vibration band located at 2887 and corresponding to the C-H stretching from the aliphatic chain showed a decrease in intensity during laser irradiation.”
Spectroscopic Characterization of Emulsions Generated with a New Laser-Assisted Device DOI: 10.3390/molecules25071729 -
Hydroxyl (O-H) zaupanje 1,0
“The H-O-H stretching vibrations of a collection of water molecules engaged in crystallization are restretching vibrations of a collection of water molecules engaged in crystallization are stretching vibrations of a collection of water molec”
Synthesis and Characterization of New Composite Materials Based on Magnesium Phosphate Cement for Fluoride Retention DOI: 10.3390/ma16020718 -
Alkyl C-H zaupanje 0,8
“Intense spectra in group 2887-2925 attributed to CH2/CH3.”
Potato Starch Utilization in Ecological Loose-Fill Packaging Materials—Sustainability and Characterization DOI: 10.3390/ma13061390 -
Alkyl C-H zaupanje 0,7
“Context: C-H stretching at three frequencies.”
Alghamdi 等 - 2021 - Effects of various media on micellization, adsorpt DOI: 10.1098/rsos.211527
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