What absorbs at 2070 cm⁻¹ in an FTIR spectrum?
A band near 2070 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 7 cited sources
Stutt svar
A band near 2070 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
Mögulegar úthlutun virkra hópa
| Virkur hópur | Stuðningsstaðreyndir | Tilvitnuð heimildir | Mesta öryggi |
|---|---|---|---|
| Adsorbed carbon monoxide | 2 | 2 | 1,0 |
| C=n | 1 | 1 | 1,0 |
| Carbon dioxide | 1 | 1 | 1,0 |
| Thiocyanate | 1 | 1 | 0,8 |
Röðun endurspeglar uppsöfnuð ritrýnisgögn, ekki eina valdboðsreglu. Staðfestu alltaf í samhengi við sýnið þitt.
Rófrök
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 2070 cm⁻¹ is usually not enough for material identification by itself.
Raunveruleg notkun
Þessi tegund fyrirspurna er algeng við auðkenningu fjölliða, skimun óþekktra plasttegunda, bilanaleit í gæðaeftirliti, staðfestingu endurunnins efnis og bókmenntabakkaða endurskoðun á hápunktum.
Algeng mistök
- Meðhöndla eina einangraða öldulengd sem sönnun á efni án þess að athuga að minnsta kosti einn eða tvo stuðningstoppa.
- Hunsa skörun: mörg virkir hópar geta lagt sitt af mörkum nálægt sömu bylgjutölunni.
- Að sleppa staðfestingu þegar aukefni, blöndur, oxun eða mengun geta brenglað litrófið.
Staðfestingarráðgjöf
Þegar tvíræðni er eftir, staðfestu tilgátuna með DSC, GC-MS eða TGA, sérstaklega fyrir blöndur, niðurbrotin sýni og fylltar fjölliður.
Ritlist á bak við þessar úthlutanir
-
öryggi 1,0
“Lack for 1 h at 323 K) on fresh surface (top spectrum) reveals a of oxidized Pd adsorption sites due to the reducing effect of set of vibrational features at 2070, 1980, 1931, 1504, 1463, CO also enables us to rule out the presence of carbo”
Sulfur Poisoning and Regeneration Behavior of Perovskite-Based NO Oxidation Catalysts DOI: 10.1007/s11244-016-0721-9 -
Adsorbed carbon monoxide öryggi 1,0
“The absorption peak observed at 2070 cm-1 is due to 0.05 linearly adsorbed CO on the Pt surface [1].”
Setup, sensitivity and application of thin electrolyte layer ATR-FTIR spectroscopy DOI: 10.1016/j.jelechem.2004.01.028 -
Adsorbed carbon monoxide öryggi 1,0
“cm-1), 2300-2400 625-725 carbon monoxide (CO: cm-1), 2000-2200 sulfide carbonyl (COS: double peaks at 2070;”
Kinetic analysis of the thermal decomposition of a carbon fibre-reinforced epoxy resin laminate DOI: 10.1016/j.jaap.2017.07.002 -
Carbon dioxide öryggi 1,0
“This result clearly indicates that the three peaks at 2041, 2021, and 2070 cm-1 are not associated with just one molecule of Co2(CO)8.”
Wang Hang 等 - 2013 - In situ FTIR study of low-pressure hydroformylatio DOI: 10.1016/S1872-2067(11)60504-4 -
C=n öryggi 1,0
“2070 cm-1 C=N stretch, 3000 cm-1 C-H stretch c.”
Walters 等 - 2005 - Structure of a-C N H prepared from ammonia DOI: 10.1557/JMR.2005.0423 -
öryggi 0,9
“Band at 2070-2030 due to CO on Rh”
Structure and reactivity of Au–Rh bimetallic clusters on titanate nanowires, nanotubes and TiO2(110) DOI: 10.1016/j.cattod.2011.06.002 -
Thiocyanate öryggi 0,8
“Text: 'shoulder at 2070' and 'SCN-'”
Johnson 等 - 2021 - An ultrafast vibrational study of dynamical hetero DOI: 10.1063/5.0044822
Ertu með róf með þessu bandi?
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